Nitration and Purification of Bromobenzene Abstract: An electrophilic aromatic substitution reaction was performed on bromobenzene with nitric acid producing both 2-bromonitrobenzene and 4-bromonitrobenzene. Products of the reaction were purified through multiple recrystallizations and column chromatography creating multiple crops of a yellow powder. The percent yield of products was determined to be 51%. The melting point of Crop 1 was found to be 110-115 °C‚ and Crop 2 was found to be 37-90
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163 CHAPTER 13 HYDROCARBON Hydrocarbons are composed of Carbon and hydrogen. The important fuels like Petrol‚ kerosene‚ coal gas‚ CNG‚ LPG etc. are all hydrocarbons or their mixture. Sources: Petroleum and natural gas are the major sources of aliphatic hydrocarbon while coal is an important source of aromatic hydrocarbons. The oil trapped inside the rocks is known as petroleum. PETRA – ROCK‚ OLEUM – OIL. The oil in the petroleum field is covered with a gaseous mixture known as natural
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Abstract The aliphatic and aromatic hydrocarbon are can be differentiate by .For example‚in the experiment involving aliphatic hydrocarbon which is cyclohexane that undergo the reaction with bromine water in the presence of UV light.This reaction is known as substitution reaction.The cyclohexane that react with bromine under present of UV light will change to slightly brown while the other one has no changeous which is still brown.For baeyer’s test‚the alkane which is heptanes will not undergo the
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BIOREMEDIATION INTRODUCTION:- The process of bioremediation was reportedly devised by George M Robinson in the 1960 during experimentation with dirty jars and the introduction of microbes this was however not applied until the 1972 clean out of the fuel holding tanks on the RMS queen mary. Science 1972 bioremediation has become greater developed as a means of cleaning up spills of gasoline diesel ‚ heavy metals and other easily degraded petroleum products (National Research Council 1993). Bioremediation
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Electrophilic Aromatic Substitution: Bromination of Aromatic Compounds Introduction: The experiment focuses on finding out what kind of activating effects that four different substituents will have on an aromatic benzene ring. The substituents being tested are aniline‚ anisole‚ acetamide (acetanilide)‚ and phenol. All four of these groups are either para or ortho activating. Bromination is the reaction that will be carried out. The melting point ranges of the final products will be taken in order
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UNIVERSITY TUNKU ABDUL RAHMAN FACULTY OF SCIENCE BACHELOR OF SCIENCE(HONS)BIOCHEMISTRY YEAR 1 SEMESTER 1 UDEC1164 ORGANIC CHEMISTRY Name: Cheong Wai See Student ID: 1404057 Practical Group: 1 Title of Experiment: Name of Tutor: Dr. Mohammod Aminuzzaman Date: 24 February 2016 Tiltle: Nitration of Methyl Benzoate Objectives: -To prepare methyl-3-nitrobenzoate from nitration of methyl benzoate by electropilic aromatic substitution. -To calculate the percentage yield and get the melting point of methyl-3-nitrobenzoate
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Preparation of 4-bromoaniline Introduction Aromatic compounds tend to undergo electrophilic aromatic substitutions rather than addition reactions. Substitution of a new group for a hydrogen atom takes place via a resonance-stabilized carbocation. As the benzene ring is quite electron-rich‚ it almost always behaves as a nucleophile in a reaction which means the substitution on benzene occurs by the addition of an electrophile. Substituted benzenes tend to react at predictable positions. Alkyl groups
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Title: Nitration of Methyl Benzoate Objective: To prepare methyl-3-nitrobenzene from nitration of methyl benzoate. Results and calculations: Density = 1.094 g/ml = Mass of methyl benzoate = 1.094 g/ml x 2.8 ml = 3.0632 g no. of mol of methyl benzoate = = 0.022499 mol 1 mol of methyl benzoate produced 1 mol of methyl m-nitrobenzene. Therefore‚ 0.022499 mol of methyl benzoate produced 0.022499 mol of methl
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ChemActivity 10: Exercises 1. Draw a complete mechanism including the intermediate and most likely product for the reaction of each alkene below with H-X. H + H Cl + Cl Cl + + Br H Br H I Br + H I H + I H 2. Draw a complete mechanism of each pair of reactant including any favorable rearrangements and all important resonance structures of all intermediates. Reactant Pair 1 Cl H Br 1 + Cl No shift stable benzylic carbocation H: shift H H Br
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Compounds containing aromatic groups are widespread in nature‚ and for this reason chemists who aim to synthesize naturally occurring compounds in the laboratory often need to introduce substituents to aromatic rings. In the organic synthesis laboratory‚ electrophilic aromatic substitutions which result in the formation of new carbon-carbon bonds are called ‘Friedel-Crafts’ alkylations and acylations‚ named for Charles Friedel of France and James Crafts of the United States‚ who together developed
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