Experiment 19 - Determination of the equilibrium constant for the reaction Fe3+ (aq) + SCN( (aq) = FeSCN2+ (aq) Object: To determine the equilibrium constant by a colorimetric method Theory: Colorimetric methods of analysis are usually applied to the determination of small concentrations of either inorganic or organic materials in a solution. The constituent sought must be coloured or must be capable of reacting with a reagent to produce a substance having a suitable colour. Beers Law‚ which
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DATE PERFORMED: JANUARY 6‚ 2011 SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION ABSTRACT The objective of the experiment was to determine the equilibrium constant of the reaction forming ferric thiocyanate through the use of Spectrophotometry. For the calibration‚ five standard solutions were prepared‚ then their respective absorbance values that were obtained through the use of the spectrophotometer‚ were plotted versus the concentration of the analyte so that a calibration
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SPECTROPHOTOMETRIC DETERMINATION OF THE EQUILIBRIUM CONSTANT OF A REACTION Methodology The following stock solutions were prepared: 1.0 M HCl‚ 0.1 M HCl‚ 0.1 M KSCN‚ 0.002 M KSCN (in 0.1 M HCl)‚ 0.2 M FeCl3 (in 0.1 M HCl)‚ and 0.002 M FeCl3(in 0.1 M HCl). Using the prepared stock solutions‚ the standard (Table 1) and Unknown (Table 2) solutions were prepared. Table 2. Preparation of Standard Solutions 0.10 M KSCN 0.002 M FeCl3 0.1 M HCl Blank 2.0 ml 0.0 ml 8 ml S1 2.0 ml 0.1 ml 7
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and has a density of 1.84 g/mL. Calculate the molarity of concentrated sulfuric acid. (A) 0.184 M (B) 9.20 M (C) 10.0 M (D) 15.6 M (E) 18.4 M 5. The activation energy of a reaction is 37.6 kJ/mol and the rate constant is 5.4 x 10-3 s-1 at 45°C. What is the rate constant at 145°C? (A) 0.16 (B) 5.4 x 10-3 (C) 8.4 x 10-3 (D) 0.38 (E) 0.56 6. Which of the following statements is correct for the reaction 2H2 + O2 → 2H2O(g)? (A) The rate of O2 disappearance is twice the rate of
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Photoelectric Effect: Determining Planck’s Constant Friday‚ Section 006 TA: Yilikal Ayino John Greavu with Daniel Erickson & Kevin Haar January 31‚ 2014 PreLab Up until the eighteenth century‚ particle theories of light dominated physics‚ primarily due to the work of Isaac Newton. Thomas Young’s 1805 famous double-slit experiment‚ which showed that light mimics a wave‚ extinguished some of these early views. However‚ in 1887‚ Heinrich Hertz – who is‚ coincidentally‚ perhaps better known for definitively
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acceleration and applied force when the total system mass is held constant (Constant Mass)‚ and the relationship between acceleration and total mass when the applied force is held constant (Constant Force). Apparatus Figure 1 Materials/Apparatus Parts • Cart and Cart ramp • Ultra Pulley + Photogate • C Clamp to mount Smart Pulley/Photogate • Vernier Lab Pro • Logger Pro • Mass Set and 1 Hanger • Block Masses • C Clamp Procedure Constant Mass 1. We made sure that the apparatus is set up as shown in
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Spectrophotometric Determination of the Equilibrium Constant of a Reaction DEPARTMENT OF MATERIALS‚ METALLURGICAL AND MINING ENGINEERING‚ COLLEGE OF ENGINEERING July 26‚ 2012 ------------------------------------------------- ABSTRACT ------------------------------------------------- Before proceeding to test the next solution‚ we must first clean the cuvette‚ using similar steps earlier. First‚ we rinse with water‚ then with the solution‚ and then we fill it up and test
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DETERMINING THE EQUIVALENT MASS AND DISSOCIATION CONSTANT OF AN UNKNOWN WEAK ACID BY TITRIMETRY INTRODUCTION Acids are substances that donate hydrogen ions and bases are substances that accept hydrogen ions. Acids and bases react with each other by transferring hydrogen ions. One way to distinguish an acid is by its equivalent mass‚ which is the number of grams of the acid needed to transfer one mole of hydrogen ion to a base. For a monoprotic acid‚ which only transfers one hydrogen ion‚ its
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Determination of Formation Constant‚ Kf of Thiocyanoiron(III)‚ FeSCN+2 Dr. Fred Omega Garces Chemistry 201 Miramar College Chemical Equilibrium: Finding the Formation Constant of FeSCN2+ (aq) Fe3 +(aq) iron(III) + SCN–(aq) FeSCN2+(aq) D thiocyanate thiocyanoiron(III) kf = € FeSCN2 + [ ] Fe +3 [SCN− ] [ ] Objective The purpose of this experiment is to determine the constant formation‚ Kf‚ (equilibrium constant) for the formation of thiocyanoiron(III)
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Chemical Equilibrium: Le Chatelier Principle By Sarah Ramos and Kristina Todorovic Chemistry 203 DEN Dr. Mohamed El-Maazawi Part A. Acid-Base Indicators Purpose In this part of the experiment‚ we will find a reagent that will shift the acid-base equilibrium reaction described by Equation (2) in one direction and then a second reagent that will cause the equilibrium position to shift back in the opposite direction. Introduction An acid–base indicator
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