General Chemistry II Determining of the equilibrium constant for the formation of FeSCN2+ Introduction The objective of this experiment was to determine the equilibrium concentration and then determine Kc. A dilution calculation was formed to determine the concentration of SCN- and Fe(SCN)2+. Each cuvette was filled to the same volume and can be seen in table 1. Then the absorbances were recorded from each cuvette and can be seen in table 1. A Beer’s law plot was made from the data that was recorded
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The Equilibrium Constant of an Ester Hydrolysis Reaction CHM 152LL Section 33263 March 28‚ 2014 John Weide Abstract: The purpose if this experiment is to determine the equilibrium constant of an unknown alcohol. In this experiment unknown alcohol number three and unknown ester number three were used. The equilibrium constant was found by titrating a series of reactions containing H2O‚ HCl‚ and the unknown ester with only the last solution containing the unknown alcohol
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reaction and the rate of the reverse reaction equal each other. At this point‚ the concentrations do not change with time. These reactions are said to be in equilibrium. Equilibrium is depended on a particular temperature‚ and the concentrations of reactants and products have to follow a rule demonstrated by the equilibrium constant Kc. The equilibrium concentrations that will be studied is the reaction between iron (III) ion and thiocyanate ion: The mixture of Fe3+ and SCN- react to form a compound
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LAB REPORT 4 DETERMINING AN EQUILIBRIUM CONSTANT CAUSION 1. Potassium thiocyanate (KSCN) is hazardous 2. Wear protective material before performing the experiment. INTRODUCTION This experiment outlines the techniques necessary to determine the equilibrium constant for the formation of an iron(III) thiocyanate complex ion (FeSCN2+) from Fe3+ and SCN- . The quantitative preparation of several solutions and subsequent measurement of the solution absorbance
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Determination of Equilibrium Constants Introduction Bromothymol blue is an indicator for many acid-base titrations. When adding different solutions within the indicator it is to react and change colors‚ in this experiment the different colors were blue‚ green‚ and yellow. In the following experiment‚ obtaining the absorbance levels for each one makes it possible to calculate the equilibrium constant. Materials and Methods For this specific experiment there are a few materials that are crucial
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CHM 096 TUTORIAL 2 (Chemical Equilibrium) Jan 2013 1. Write the equilibrium constant expression‚ Kc‚ for each of the following reactions: a) b) c) d) e) f) 2NO(g) + O2(g) ⇄ 2NO2(g) The decomposition of solid potassium chlorate to solid potassium chloride and oxygen gas. 4HCl(g) + O2(g) ⇄ 2H2O(g) + 2Cl2(g) 2NO2(g) + 7H2(g) ⇄ 4H2O(l) + 2NH3(g) H2O(g) + C(s) ⇄ CO(g) + H2(g) The reduction of solid copper (II) oxide with hydrogen gas to produce copper metal and water at o 500 C. 2H2(g) + O2(g)
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is considered in a state of equilibrium when its properties do not change at time passes. Equilibrium is a state of a reaction where the concentration of all the reactants and all the products remain constant over time. Equilibrium as used in chemical systems means that all the chemical forces in a reaction are in balance and that all physical properties of the system (color‚ density and concentration) of all chemicals species involved remains constant. The equilibrium state can be characterized by
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CH 127 – Chem 2 Lab Determination of an Equilibrium constant Goals The purpose of this experiment is to determine the equilibrium constant for the reaction Fe3+(aq) + HSCN(aq) –>FeSCN2+(aq) + H+(aq). The equilibrium constant expression Kc for Reaction is kc=FeSCN2+[H+]Fe3++[HSCN] Procedure *Preparation of the Beer’s law plot Prepare five solutions of FeSCN2+(aq) of known concentrations between 1x10-5M and 1x10-4M by diluting various volumes of 4.62x10-4 HSCN. Calculate the Final concentration
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Determination of an Equilibrium Constant Abstract: In this experiment‚ two reactions were run to determine the molar absorptivity and the equilibrium constant of FeSCN2+. The main principles used in this lab are equilibrium‚ LeChatlier’s Principle‚ Beer’s Law and Spectrocopy. The first reaction was run to completion using LeChatier’s Principle and the second reaction was run to equilibrium. A spectrophotometer was used to measure absorbances. Using a graph of absorbance versus concentration
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Spectrophotometric Determination of an Equilibrium Constant Introduction: In this experiment‚ you will study the reaction between aqueous iron (III) nitrate‚ Fe(NO3)3‚ and potassium thiocyanate‚ KSCN. They react to produce the blood-red complex [Fe(SCN)]2+. Fe3+ + SCN- ( [Fe(SCN)]2+ The equilibrium constant expression may be expressed as: K = [pic] You will prepare a series of standard solutions that contain known concentrations of [Fe(SCN)]2+ and will determine
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