Determining an Enthalapy Change of Reaction Purpose of Experiment The purpose of this experiment is to determine the enthalapy change for the displacement reaction: Zn(s) + CuSO4(aq) Cu(s) + ZnSO4(aq) Hypothesis With this experiment I can also not make a hypothesis‚ because we did actually not do the experiment‚ but we were told that the temperature would make a sudden drop ‚ but we can measure the ΔT of the surrounding. The reaction is endothermic because the system will take in energy
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Enthalpy of Displacement IB Topic: Energetics Assessment Criteria: DCP‚ CE DATA COLLECTION AND PROCESSING ASPECT MARKS AWARDED Recording raw data: Processing raw data: Presenting Proceeded data: TOTAL: CONCLUSION AND EVALUATION Conclusion Evaluation Improving the procedure TOTAL AIM: Experimentally determine the enthalpy change of the displacement reaction between zinc and copper sulphate. Zn (s) + CuSO4 (aq) Cu (s) + ZnSO4
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Hess’ Law of Heat Summation Hess’ Law states that: "The enthalpy change for any reaction depends on the products and reactants and is independent of the pathway or the number of steps between the reactant and product". BASICALLY: Hess’ Law states "the heat evolved or absorbed in a chemical process is the same whether the process takes place in one or in several steps" >This is also known as the "law of constant heat summation". All it means is that no matter how many steps the chemical
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24.31g/mol = 0.01275 moles no of moles of HCl = molarity x volume = 1.0M x (25/1000)mL = 0.025 moles heat of reaction will be 0.025 moles as HCL act as the limiting reactant. Enthalpy change of the reaction‚H2 Volume of HCL solution = 25 mL Assume the solution has the same density and specific heat capacity as water. Volume of HCL solution = 25 mL ρ = mass/volume 1.0g/cm³ = mass/ 25 cm³
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Enthalpy changes can be calculated using average bond enthalpy data. i) The enthalpy change to convert methane into gaseous atoms is shown below. [pic] Calculate the average bond enthalpy of a C—H bond in methane. [1] ii) Use the data in the table below and your answer to (a)(i) to calculate the enthalpy change for [pic] [3] [pic] b) The standard enthalpy of formation of 1‚2-dibromoethane‚ CH2BrCH2Br‚ is – 37.8 kJmol-1. Suggest the main reason for
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Energetics Practical 2: To Determine the Enthalpy Change of a Reaction Background Calcium Carbonate‚ CaCO₃‚ decomposes with heat to form CaO and CO₂. The objective of this practical was to determine the enthalpy change for this reaction by using an indirect method based upon the foundation of Hess’ Law. Both calcium oxide and calcium carbonate react readily with 2 mol/dm3. The reaction can be demonstrated as so: CaCO₃ (s) -> CaO(s) + CO₂ (g) Results: Raw Data Calcium Carbonate Mass of CaCO₃
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The Advanced Placement Examination in Chemistry Part II - Free Response Questions & Answers 1970 to 2007 Thermodynamics Teachers may reproduce this publication‚ in whole or in part‚ in limited print quantities for non-commercial‚ face-to-face teaching purposes. This permission does not apply to any third-party copyrights contained within this publication. Advanced Placement Examination in Chemistry. Questions copyright© 1970-2007 by the College Entrance
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measuring enthalpy changes In all the following questions‚ assume that the densities and specific heat capacities of the solutions are the same as pure water i.e. ρ = 1.0 gcm-3 and c = 4.18 Jg-1K-1 1. Zinc will displace copper from copper (II) sulphate solution according to the following equation: CuSO4(aq) + Zn(s) ( Cu(s) + ZnSO4(aq) If an excess of zinc powder is added to 50 cm3 of 1.0 moldm-3 copper(II) sulphate‚ the temperature increases by 6.3 oC. Calculate the enthalpy change
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Calorimetry 1. How many calories would it take to raise the temperature of 200 g of water 100oC? 2. It takes 23.5 J to raise the temperature of 10.0 g of silver by 10oC. What is the specific heat of silver? 3. A 255 g quantity of gold is heated from 28oC to 100oC. How many joules of energy were used? (specific heat of gold = 0.13 J/goC) 4. What will be the final temperature of 5.00 g of silver at 37oC if it gives off 25.0 J of heat to the surroundings
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THERMOCHENISTRY Index 1.0 Introduction | | | | | | | | 1 | 2.0 Enthalpy Changes | | | | | | | 2‚3 | 2.1 The Standard Conditions For Calculating Enthalpy Changes | | | | 3.0 Hess’s Law | | | | | | | | 4‚5 | 3.1 The Applications of Hess’s Law | | | | | | 4.0 Standard Molar Enthalpy Change of Formation‚ ΔHof | | | | 6‚7 | 4.1 The Stability of A Compound | | | | | | | 4.2 Using ΔHof
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