CH 127 – Chem 2 Lab Determination of an Equilibrium constant Goals The purpose of this experiment is to determine the equilibrium constant for the reaction Fe3+(aq) + HSCN(aq) –>FeSCN2+(aq) + H+(aq). The equilibrium constant expression Kc for Reaction is kc=FeSCN2+[H+]Fe3++[HSCN] Procedure *Preparation of the Beer’s law plot Prepare five solutions of FeSCN2+(aq) of known concentrations between 1x10-5M and 1x10-4M by diluting various volumes of 4.62x10-4 HSCN. Calculate the Final concentration
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Determination of Equilibrium Constants Introduction Bromothymol blue is an indicator for many acid-base titrations. When adding different solutions within the indicator it is to react and change colors‚ in this experiment the different colors were blue‚ green‚ and yellow. In the following experiment‚ obtaining the absorbance levels for each one makes it possible to calculate the equilibrium constant. Materials and Methods For this specific experiment there are a few materials that are crucial
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is considered in a state of equilibrium when its properties do not change at time passes. Equilibrium is a state of a reaction where the concentration of all the reactants and all the products remain constant over time. Equilibrium as used in chemical systems means that all the chemical forces in a reaction are in balance and that all physical properties of the system (color‚ density and concentration) of all chemicals species involved remains constant. The equilibrium state can be characterized by
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Determination of an Equilibrium Constant Abstract: In this experiment‚ two reactions were run to determine the molar absorptivity and the equilibrium constant of FeSCN2+. The main principles used in this lab are equilibrium‚ LeChatlier’s Principle‚ Beer’s Law and Spectrocopy. The first reaction was run to completion using LeChatier’s Principle and the second reaction was run to equilibrium. A spectrophotometer was used to measure absorbances. Using a graph of absorbance versus concentration
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Spectrophotometric Determination of an Equilibrium Constant Introduction: In this experiment‚ you will study the reaction between aqueous iron (III) nitrate‚ Fe(NO3)3‚ and potassium thiocyanate‚ KSCN. They react to produce the blood-red complex [Fe(SCN)]2+. Fe3+ + SCN- ( [Fe(SCN)]2+ The equilibrium constant expression may be expressed as: K = [pic] You will prepare a series of standard solutions that contain known concentrations of [Fe(SCN)]2+ and will determine
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Spectrophotometric Determination of an Equilibrium Constant. Abstract: The report presents determination of equilibrium constant for the formation of a complex ion FeSCN2+. This was accomplished using a colorimeter to measure absorbance of some known concentration solutions in order to generate the calibration curve. The equation of the graph was used to compute the equilibrium concentrations of the reactants and products‚ needed to calculate the equilibrium constant for the reaction
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this experiment equilibrium. Esterification is a slow and reversible reaction. The equation for the reaction between an acid RCOOH and an alcohol RẬᶦ can be the same or different; at equilibrium‚ the concentrations of both reactants and products are constant. In this experiment set up‚ the reaction between ethanoic acid and ethanol to produce ethyl ethanoate and water is a reversible reaction as shown by the following equation: CH₃COOH + CH₃CH₂OH↔CH₃COOCH₂CH₃ +H₂O The Equilibrium Law states that
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SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT OF A REACTION UNIVERSITY OF THE PHILIPPINES‚ DILIMAN QUEZON CITY‚ PHILIPPINES August 2‚ 2013 ABSTRACT The objective of this experiment is to determine the equilibrium constant‚ denoted Keq‚ for the formation of [Fe(SCN)]2+ complex which is a product of the reaction between the ions Fe3+ and SCN-. In performing this experiment‚ solutions containing FeCl3 and KSCN‚ diluted in HCl‚ were measured for their absorbance using a UV-Vis
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DATE PERFORMED: JULY 20‚ 2007 SPECTROPHOTOMETRIC DETERMINATION OF EQUILIBRIUM CONSTANT FOR A REACTION ABSTRACT UV-VIS spectrophotometry is one of the most widely-used methods for determining and identifying many inorganic species. During this experiment‚ this spectrophotometry was used to determine the equilibrium constant‚ Keq‚ of the Fe3+(aq)+SCN-(aq)↔ FeSCN2+(aq) reaction. By determining the amount of light absorbed‚ the concentration of the colored FeSCN2+ solution was also quantitatively
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Date Performed: January 10 & 15‚ 2013 Spectrophotometric Determination of the Equilibrium Constant of a Reaction R.J.V. Ortega and J.C.V. Gatdula Institute of Chemistry‚ College of Science University of the Philippines‚ Diliman‚ Quezon City‚ Philippines Received January 22‚ 2013 ------------------------------------------------- ------------------------------------------------- ------------------------------------------------- ABSTRACT -------------------------------------------------
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