Sustainable Chemistry

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Toward Sustainable Chemistry

   Terry Collins*

Chemistry has an important role to play in achieving a sustainable civilization on Earth. The present economy remains utterly dependent on a massive inward flow of natural resources that includes vast amounts of nonrenewables. This is followed by a reverse flow of economically spent matter back to the ecosphere. Chemical sustainability problems are determined largely by these economy-ecosphere materials flows (see the figure, below), which current chemistry education essentially ignores. It has become an imperative* that chemists lead in developing the technological dimension of a sustainable civilization.

When chemists teach their students about the compositions, outcomes, mechanisms, controlling forces, and economic value of chemical processes, the attendant dangers to human health and to the ecosphere must be emphasized across all courses. In dedicated advanced courses, we must challenge students to conceive of sustainable processes and orient them by emphasizing through concept and example how safe processes can be developed that are also profitable. Green or sustainable chemistry† can contribute to achieving sustainability in three key areas. First, renewable energy technologies will be the central pillar of a sustainable high-technology civilization. Chemists can contribute to the development of the economically feasible conversion of solar into chemical energy and the improvement of solar to electrical energy conversion. Second, the reagents used by the chemical industry, today mostly derived from oil, must increasingly be obtained from renewable sources to reduce our dependence on fossilized carbon. This important area is beginning to flourish, but is not the subject of this essay. Third, polluting technologies must be replaced by benign alternatives. This field is receiving considerable attention, but the dedicated research community is small and is merely scratching the surface of an immense problem that I will now sketch. Many forces give rise to chemical pollution, but there is one overarching scientific reason why chemical technology pollutes. Chemists developing new processes strive principally to achieve reactions that only produce the desired product. This selectivity is achieved by using relatively simple reagent designs and employing almost the entire periodic table to attain diverse reactivity. In contrast, nature accomplishes a huge range of selective biochemical processes mostly with just a handful of environmentally common elements. Selectivity is achieved through a reagent design that is much more elaborate than the synthetic one. For example, electric eelscan store charge via concentration gradients of iochemically commonalkali metal ions across the membranes of electroplaque cells. In contrast, most batteries used for storing charge require biochemicallyforeign, toxic elements, such as lead and cadmium. Because of thisstrategic difference, manmade technologies often distribute throughoutthe environment persistent pollutants that are toxic because theycontain elements that are used sparingly or not at all in biochemistry.

Persistent bioaccumulative pollutants pose the greatest chemical threat to sustainability. They can be grouped into two classes. Toxic elements are the prototypical persistent pollutants; long-lived radioactive elements are especially dangerous examples. New toxicities continue to be discovered for biologically uncommon elements. The second class consists of degradation-resistant molecules. Many characterized examples originate from the chlorine industry‡ and are also potently bioaccumulative. For example, polychlorinated

dibenzo-dioxins and -furans (PCDDs and PCDFs) are deadly, persistent organic pollutants. They can form in the bleaching of wood pulp with chlorine-based oxidants, the incineration of chlorine-containing compounds and organic matter, and the recycling of metals. The United Nations Environmental Program...
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