Preview

Preparing Esters by Esterification Method Using Carboxylic Acid to an Alcohol, Which Is 1.0 Ml of Ethanoic Acid to the Ethanol, and Ethanoic Acid to the Propan-1-Ol, Also Adding H2So4 as a Catalyst for the Reaction

Better Essays
Open Document
Open Document
2014 Words
Grammar
Grammar
Plagiarism
Plagiarism
Writing
Writing
Score
Score
Preparing Esters by Esterification Method Using Carboxylic Acid to an Alcohol, Which Is 1.0 Ml of Ethanoic Acid to the Ethanol, and Ethanoic Acid to the Propan-1-Ol, Also Adding H2So4 as a Catalyst for the Reaction
Preparing Esters by esterification method using carboxylic acid to an alcohol, which is 1.0 ml of ethanoic acid to the ethanol, and ethanoic acid to the propan-1-ol, also adding H2SO4 as a catalyst for the reaction

Abstract:
Esters are a group of organic compound, famous for their interesting odours and smells. In this investigation student used ethanoic acid and ethanol with sulfuric acid as catalyst to produce ester, which was known of its smell. However it was expected to have a pleasant smell, but it has a smell like a nail polish in cold water and a vinegar in hot water. While the second test was ethanoic acid and propan-1-ol and it has a similar smell like that of ethanoic acid and ethanol, although the product of ethanoic acid and ethanol had a stronger smell but both of them smelled like nail polish remover plus a little vinegar. It was expected to have a pleasant smell, but the characteristic flavors and fragrances nature are due to compounds with the ester functional group. It was done properly overall.
Introduction:
Esters have a very sweetly fruity smell. Obviously occurring esters are found in fruits. An ester is the product of the reaction between an acid (usually organic) and an alcohol. Esters essentially result from the condensation (a reaction that produces water) of a carboxylic acid and an alcohol. The process is called esterification. This reaction can be catalyzed by the presence of H+ ions. However H2SO4 is often used as a catalyst for this reaction. This is the most common method for making esters.
R-OH + R’-COOH ←→ R’-COO-R + H2O
Esterification is an equilibrium reaction, which means that the reaction does not completely go to completion, and it is not likely to get a 100% yield of ester by this method. To overcome this difficulty, a large excess of one of the reagents (typically the alcohol) is used along with a drying agent. Both of these strategies have the effect of changing the equilibrium to the right and increasing the production of



References: "ESTERS." Welcome to Hartnell College!!. N.p., n.d. Web. 12 Dec. 2012. <http://www.hartnell.cc.ca.us/faculty/shovde/chem12b/esters.htm>. "ESTERS An Introduction to Organic Chemistry Reactions." Esters-intro organic rxns.DOC. David A. Katz, n.d. Web. 12 Dec. 2012. <https://docs.google.com/viewer?a=v&q=cache:N_rscs1OG40J:www.chymist.com/Esters%2520-%2520Introduction.pdf+how+can+i+improve+ "Lab Preparation and Purification of an Ester." The Upper Canada District School Board. N.p., n.d. Web. 12 Dec. 2012. <http://www2.ucdsb.on.ca/tiss/stretton/chem "Organic Chemistry- Esters Lab & Lab Report (Making Scents of Esters)."Scribd. Mark Riley, n.d. Web. 12 Dec. 2012.

You May Also Find These Documents Helpful

  • Better Essays

    Purpose: The purpose of this experiment is to synthesize Isopentyl Acetate using a Fischer esterification reaction. Fischer esterification is an acid-catalyzed condensation of an alcohol and a carboxylic acid, yielding an ester and water. Isopentyl Acetate has the scent of banana oil, once synthesized it will be purified by distillation. Then the analysis of the sample using H NMR and IR will determine purity of the product.…

    • 1537 Words
    • 7 Pages
    Better Essays
  • Good Essays

    Experiment 13B

    • 972 Words
    • 4 Pages

    A reflux condenser was assembled using a 25-mL round-bottom flask, hot plate, and aluminum block. It was equipped with a drying tube filled with calcium chloride to control vapors. Approximately 2.5 mL of isopentyl alcohol was massed and placed in the round-bottom flask that contained a stir bar. Using the same graduated cylinder, about 3.5 mL of glacial acetic acid was added to the flask. A calibrated Pasteur pipet was used to add 0.5 mL of concentrated sulfuric acid to the flask and the flask was mixed immediately. The flask was connected to the apparatus and covered with aluminum foil to help retain heat. Using rubber tubing, water was circulated into the lower attachment and out the top attachment and the mixture was brought to a boil. After heating under reflux for 60-75 minutes, the flask was removed from the heating source and left to cool down to room temperature. The reaction mixture from the flask was transferred to a culture tube and 5-mL of water was added. Upon addition of water, careful shaking, and occasional venting, the phases separated and the lower aqueous layer was removed and discarded. Using the same procedure as explained above with water, 2.5 mL of aqueous sodium bicarbonate was added and the lower aqueous layer was again removed and discarded. The same procedure was repeated one last time with 2.5 mL of saturated aqueous sodium chloride and the lower aqueous layer was removed and discarded, leaving behind the crude ester. The crude ester was transferred to…

    • 972 Words
    • 4 Pages
    Good Essays
  • Satisfactory Essays

    b) Ethanoic acid can be reacted with methanol to form an ester, which is used…

    • 390 Words
    • 3 Pages
    Satisfactory Essays
  • Good Essays

    Grignard Reaction Lab

    • 1231 Words
    • 5 Pages

    In addition to a very good example; forming an ester is possible by reacting Grignard reagent with alpha-monochloroether.…

    • 1231 Words
    • 5 Pages
    Good Essays
  • Powerful Essays

    exp 12

    • 1505 Words
    • 7 Pages

    Introduction: The purpose of this experiment is to synthesize isopentyl acetate via an esterification reaction…

    • 1505 Words
    • 7 Pages
    Powerful Essays
  • Good Essays

    For the percentage yield is 39.08% which is less than and not 100%, by this, it can be concluded that the reaction is non-stoichiometric. The low yield can be explained by the following ways:…

    • 682 Words
    • 3 Pages
    Good Essays
  • Satisfactory Essays

    Lab 8 Isopentyl acetate 1

    • 599 Words
    • 3 Pages

    Esters are carboxylic acid derivatives in which the acyl carbon bears an ether group instead of the hydroxy group. Esters are synthesized by different methods such as an Sn2 process where a carboxylic acid is treated with a strong base followed by an alkyl halide. Fischer Esterification is a nucleophilic acyl substitution reaction that converts a carboxylic acid into an ester when the carboxyl group of an acid and the hydroxyl group of an alcohol are condensed with the expulsion of a water molecule. The by product is removed to exploit Le Chatelier’s principle in order to favor the formation of the ester over the starting material.…

    • 599 Words
    • 3 Pages
    Satisfactory Essays
  • Good Essays

    Synthesize isopentyl acetate by combining isopentyl alcohol with acetic acid and sulfuric acid and then heating the reaction mixture under reflux for an hour. The alcohol is the limiting reactant, so it should be weighed/ the acids can be measured by volume. The esterification reaction is reversible, and it has an equilibrium constant of approximately 4.2. A pure component can be obtained from a mixture by separating it from all other components of the mixture, using procedures that take advantage of differences in solubility, boiling points, acid-base properties, and other characteristics of the components. Because isopentyl acetate is a liquid, the separation and purification operations will differ from those used previously for solid products. The water that forms during the reaction will be separated from the ester along with the wash liquids. Any traces of water that remain are then removed by a drying agent, either magnesium sulfate or sodium sulfate. Because isopentyl alcohol has a lower boiling point than that of isopentyl acetate, and the by-products have higher boiling points, it should be possible- in principle- to remove the alcohol and by-products from the ester by distillation. Isopentyl alcohol should distill first, followed by the ester, and any by-products should remain behind in the pot-the vessel in which the reaction mixture is boiled.…

    • 1073 Words
    • 5 Pages
    Good Essays
  • Powerful Essays

    Chem 3650

    • 1178 Words
    • 5 Pages

    Marilyn Wooten PhD. marilyn.wooten@gmail.com 01T 7:30–11:20 am T/R Ray Still M.S. Raymond.still@gmail.com 02T 6:30 10:20 pm T/R *If you miss a lab you must email me and your lab instructor ASAP. You will have one week to make up the lab and it must be made up in one of the sections listed above. Prerequisites: Completion of or concurrent enrollment in CHE 3643. Course Outline: Simple and multistep synthesis of organic compounds. Text: There is NO text for this lab. Experimental procedures can be found on Blackboard Learn. https://learn.utsa.edu/ Lab notebooks: Instructor's discretion Grades:  60% lab reports  20% Midterm exam  20% Final exam o Exams will be over lab and lecture material. You may use your lab reports during the midterm and final Format of prelab: 1. Title of experiment 2. Abstract  A short description of the experiment 3. Include reactions (with mechanism) if applicable. 4. Structures of reactants and products. (only organic compounds)  http://www.sigmaaldrich.com  Wikipedia also has information on chemical compounds but it is community maintained, so double check the information. 5. Table of physical constants for all chemicals (this includes products)  Amount to be used, melting point, boiling point, MW, and density. o http://www.sigmaaldrich.com 6. Hazards of all chemical used in lab. (must be complete or you will be sent out)…

    • 1178 Words
    • 5 Pages
    Powerful Essays
  • Satisfactory Essays

    The technique for esterification that was employed in the experiment was to use a reflux apparatus (Figure 1) while heating in order to evaporate out water to drive our reaction into the product favored direction. The starting material of isopentyl alcohol (1.0 mL) and excess glacial acetic acid(1.5 mL, 17.6M) were eppendorf pipetted into a 5 mL conical vile. This mixture was acid catalyzed by the addition on two drops of H2SO4. The mixture was then heated to 150-160⁰C in order to increase energy for esterification to occur over a period of 60- 75 minutes.…

    • 564 Words
    • 3 Pages
    Satisfactory Essays
  • Better Essays

    Isopentyl Acetate

    • 1362 Words
    • 6 Pages

    The purpose of this experiment is to synthesize isopentyl acetate via an esterification reaction between glacial acetic acid and isopentyl alcohol, using concentrated sulfuric acid as a catalyst. The product was washed using sodium bicarbonate and water, then dried with anhydrous sodium sulfate. It was then distilled using a standard simple distillation apparatus. The percent yield of isopentyl acetate was 60.39%. This may have been low due to incomplete distillation or evaporation once entering the receiving flask. The product had a distinct “banana oil” smell, making the reaction successful.…

    • 1362 Words
    • 6 Pages
    Better Essays
  • Satisfactory Essays

    Alexander the Great

    • 671 Words
    • 3 Pages

    Fischer esterification was used in this experiment in order to synthesis isopenthyl acetate. This process involved combining…

    • 671 Words
    • 3 Pages
    Satisfactory Essays
  • Good Essays

    At the end of WM3 on page 109: 1. Instead of Chemical Ideas 13.4 read 13.4 part b, which is available on the Heinemann website. 2. Read Section 13.5 in your Chemical Ideas book which deals with naming and making esters.…

    • 2823 Words
    • 12 Pages
    Good Essays
  • Better Essays

    Esterification: the process is in 95 ~ 135 ℃ heating temperature about 2 hours, can also be used in catalyst (0.1% ~ 0.5% sodium methanol or…

    • 782 Words
    • 3 Pages
    Better Essays
  • Satisfactory Essays

    Paper

    • 294 Words
    • 2 Pages

    Process description : PTA and MEG mixed together in paste mixing tank. Mixing of paste is done by special type of agitator. The slurry obtained in paste tank is fed to esterification reactor by screw pump. The esterification reaction is carried out under pressure and at high temperature of 265 deg C . Mole ratio of 1:1.19 is maintain in the reactor. Theoretical mole ratio requirement is 1: 1.01 Monomer is the product of esterification reaction.…

    • 294 Words
    • 2 Pages
    Satisfactory Essays

Related Topics