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Composites
Composites: Part B 44 (2013) 120–127

Contents lists available at SciVerse ScienceDirect

Composites: Part B journal homepage: www.elsevier.com/locate/compositesb

Green composites: A review of adequate materials for automotive applications
Georgios Koronis ⇑, Arlindo Silva, Mihail Fontul
Instituto Superior Tecnico, Mechanical Engineering Department, Lisbon, Portugal

a r t i c l e

i n f o

a b s t r a c t
This study provides a bibliographic review in the broad field of green composites seeking-out for materials with a potential to be applied in the near future on automotive body panels. Hereupon, materials deriving from renewable resources will be preferred as opposed to the exhaustible fossil products. With the technical information of bio-polymers and natural reinforcements a database was created with the mechanical performance of several possible components for the prospect green composite. Following the review, an assessment is performed where aspects of suitability for the candidate elements in terms of mechanical properties are analyzed. In that section, renewable materials for matrix and reinforcement are screened accordingly in order to identify which hold both adequate strength and stiffness performance along with affordable cost so as to be a promising proposal for a green composite. Ó 2012 Elsevier Ltd. All rights reserved.

Article history: Received 27 December 2011 Received in revised form 7 May 2012 Accepted 3 July 2012 Available online 24 July 2012 Keywords: A. Polymer–matrix composites (PMCs) B. Mechanical properties Natural fibers

1. Introduction Green composites deriving from renewable resources bring very promising potential to provide benefits to companies, natural environment and end-customers due to dwindling petroleum resources. The shift to more sustainable constructions in automotive industry is not only an initiative towards a more viable environment and cost efficiency but also a demand of European regulations. The



References: [1] Greening transport, European commission. European parliament and the council, SEC/2008/2206 FIN [08.07.08]. [2] Herrmann AS, Nickel J, Riedel U. Construction materials based upon biologically renewable resources – from components to finished parts. Polym Degrad Stab 1998;59:251–61. Fig. 6. Ternary diagram of green composites. G. Koronis et al. / Composites: Part B 44 (2013) 120–127 [3] Alves C, Ferrão PMC, Silva AJ, Reis LG, Freitas M, Rodrigues LB. Ecodesign of automotive components making use of natural jute fiber composites. J Cleaner Prod 2011;18:313–27. [4] Jayaraman K. Manufacturing sisal–polypropylene composites with minimum fibre degradation. Compos Sci Technol 2001;63:367–74. [5] Davies G. Materials for automobile bodies. Oxford: Replika Press Pvt. Ltd.; 2003. [6] Suddell B, Evans W. Natural fiber composites in automotive applications. In: Mohanty AK, Misra M, Drzal TL, editors. Natural fibers, biopolymers, and biocomposites. CRC Press; 2005. [7] Mohanty AK, Misra M, Drzal TL, Selke SE, Harte BR, Hinrichsen G. Natural fibers, biopolymers, and biocomposites: an introduction. In: Mohanty AK, Misra M, Drzal TL, editors. Natural fibers, biopolymers, and biocom posites. Boca Raton: Crc Press-Taylor & Francis Group; 2005. p. 1–36. [8] Anonymous. Bioplastics in automotive applications. Bioplastics Mag; 2007 [cited 2 (1): 14–8] . [9] mitsubishi-motors.com. Mitsubishi Motors develops plant-based green plastic floor mat. Tokyo: Mitsubishi Motors Co. [20.06.06]. . [10] North America enviromental report, report recycling use. . [11] Stewart R. Automotive composites offer lighter solutions. Reinf Plast 2010;54:22–8. [12] toyota.com. Automotive news world congress. Detroit [11.01.11]. . [13] Anonymous. Daimler Chrysler turns to natural fibres. Reinf Plast 2000;44:21. [14] media.daimler.com. Daimler Chrysler uses a natural-fiber component in the exterior of the Mercedes-Benz A-Class. Stuttgart. [29.06.05]. . [15] Brosius D. Natural fiber composites slowly take root. Compos Technol 2006. [16] Müssig J, Schmehl M, von Buttlar HB, Schönfeld U, Arndt K. Exterior components based on renewable resources produced with SMC technology – considering a bus component as example. Ind Crops Prod 2006;24:132–45. [17] Malnati P. ECO Elise concept: lean, speedy and green composites technology; 2009;15(4):46-8 [cited August]. . [18] Chen Y, Sun LF, Chiparus O, Negulescu I, Yachmenev V, Warnock M. Kenaf/ ramie composite for automotive headliner. J Polym Environ 2005;13:107–14. ´ [19] Arbelaiz A, Fernandez B, Cantero G, Llano-Ponte R, Valea A, Mondragon I. Mechanical properties of flax fibre/polypropylene composites. Influence of fibre/matrix modification and glass fibre hybridization. Compos, Part A: Appl Sci Manuf 2005;36:1637–44. [20] Yu T, Ren J, Li S, Yuan H, Li Y. Effect of fiber surface-treatments on the properties of poly(lactic acid)/ramie composites. Compos, Part A: Appl Sci Manuf 2010;41:499–505. [21] Fatima S, Mohanty AR. Acoustical and fire-retardant properties of jute composite materials. Appl Acoust 2011;72:108–14. [22] Kumar A, Mohan A, Diwan RK, Malik A, Khandal RK. Studies on Euphorbia coagulum modified polystyrene waste jute composites: Part II. J Polym Mater 2009;26:67–79. [23] Munder F, Fürll C, Hempel H. Processing of natural fiber plants for industrial application. In: Mohanty AK, Misra M, Drzal TL, editors. Natural fibers, biopoly mers, and biocomposites. Boca Raton: Crc Press-Taylor & Francis Group; 2005. [24] Bledzki AK, Jaszkiewicz A. Mechanical performance of biocomposites based on PLA and PHBV reinforced with natural fibres – a comparative study to PP. Compos Sci Technol 2010;70:1687–96. [25] Bledzki AK. Abaca fibre reinforced PP composites and comparison with jute and flax fibre PP composites. EPRESS Polym Lett 2007;1:755–62. [26] Advanced automotive technology: visions of a super-efficient family car electric vehicle information. Washington, D.C: Office of Technology Assessment (OTA); 1995. [27] O’Donnell A, Dweib MA, Wool RP. Natural fiber composites with plant oilbased resin. Compos Sci Technol 2004;64:1135–45. [28] Mougin G. Natural fibre composites – problems and solutions. JEC composites magazine; 2006 [cited (25)]. . [29] Bismarck A, Mishra S, Lampke T. Plant fibers as reinforcement for green composites. In: Mohanty AK, Misra M, Drzal TL, editors. Natural fibers, biopolymers, and biocomposites. Boca Raton: Crc Press-Taylor & Francis Group; 2005. [30] Ashori A. Wood-plastic composites as promising green-composites for automotive industries! Bioresour Technol 2008;99:4661–7. [31] Kim J, Yoon T, Mun S, Rhee J, Lee J. Wood – polyethylene composites using ethylene–vinyl alcohol copolymer as adhesion promote. Bioresour Technol 2006;97:494–9. [32] Gassan J, Bledzki AK. Thermal degradation of flax and jute fibers. J Appl Polym Sci 2001;82:1417–22. [33] Mo XQ, Wang KH, Sun XZS. Straw-based biomass and biocomposites. In: Mohanty AK, Misra M, Drzal TL, editors. Natural fibers, biopolymers, and biocomposites. Boca Raton: Crc Press-Taylor & Francis Group; 2005. p. 473–95. [34] Wielage B, Lampke T, Marx G, Nestler K, Starke D. Thermogravimetric and differential scanning calorimetric analysis of natural fibres and polypropylene. Thermochim Acta 1999;337:169–77. [35] Ochi S. Development of high strength biodegradable composites using Manila hemp fiber and starch-based biodegradable resin. Compos, Part A: Appl Sci Manuf 2006;37:1879–83. [36] Mohanty AK, Misra M, Hinrichsen G. Biofibres, biodegradable polymers and biocomposites: an overview. Macromol Mater Eng 2000;276–277:1–24. 127 [37] Wool R, Khot SN, University of Delaware. ASM International; Bio-based resins and natural fibers; 2000. . [38] Uyama H, Kuwabara M, Tsujimoto T, Kobayashi S. Enzymatic synthesis and curing of biodegradable epoxide-containing polyesters from renewable resources. Biomacromolecules 2003;4:211–5. [39] Shogren RL, Petrovic Z, Liu ZS, Erhan SZ. Biodegradation behavior of some vegetable oil-based polymers. J Polym Environ 2004;12:173–8. [40] Suprakas SR, Mosto B. Biodegradable polymers and their layered silicate nanocomposites: in greening the 21st century materials world. Prog Mater Sci 2005;50:962–1079. [41] van Dam JEG, de Klerk-Engels B, Struik PC, Rabbinge R. Securing renewable resource supplies for changing market demands in a bio-based economy. Ind Crops Prod 2005;21:129–44. [42] John R, Nampoothiri K, Pandey A. Fermentative production of lactic acid from biomass: an overview on process developments and future perspectives. Appl Microbiol Biotechnol 2007;74:524–34. [43] Oksman K, Skrifvarsb M, Selinc JF. Natural fibres as reinforcement in polylactic acid (PLA) composites. Compos Sci Technol 2003;63:1317–24. [44] Jahan A, Ismail MY, Sapuan SM, Mustapha F. Material screening and choosing methods – a review. Mater Des 2010;31:696–705. [45] Ribeiro I, Pecas P, Silva A, Henriques E. Life cycle engineering methodology applied to material selection, a fender case study. J Cleaner Prod 2008;16:1887–99. [46] Saur K, Fava JA, Spatari S. Life cycle engineering case study: automobile fender designs. Environ Prog 2000;19:72–82. [47] Wambua P. Natural fibres: can they replace glass in fibre reinforced plastics? Compos Sci Technol 2003;63:1259–64. [48] Sedan D, Pagnoux C, Smith A, Chotard T. Mechanical properties of hemp fibre reinforced cement: Influence of the fibre/matrix interaction. J Eur Ceram Soc 2008;28:183–92. [49] George J, Sreekala MS, Thomas S. A review on interfacial modification and characterization of natural fiber reinforced plastic composites. Polym Eng Sci 2001;41:1471–85. [50] Bledzki AK, Jaszkiewicz A, Scherzer D. Mechanical properties of PLA composites with man-made cellulose and abaca fibres. Compos, Part A: Appl Sci Manuf 2009;40:404–12. [51] Bledzki AK, Mamun AA, Jaszkiewicz A, Erdmann K. Polypropylene composites with enzyme modified abaca fibre. Compos Sci Technol 2010;70:854–60. [52] Goda K, Sreekala MS, Gomes A, Kaji T, Ohgi J. Improvement of plant based natural fibers for toughening green composites – effect of load application during mercerization of ramie fibers. Compos, Part A: Appl Sci Manuf 2006;37:2213–20. [53] kenaf-fiber.com. Technical data and information about thermal insulation and soundproofing of kenaf natural fibers. Mantova: KEFI, S.p.A. [03.07.10]. . [54] Design G. CES EduPack Ver.6.2.0 materials selection software. Cambridge: Granta Design Limited; 2010. [55] Satyanarayana KG, Guimarães JL, Wypych F. Studies on lignocellulosic fibers of Brazil. Part I: source, production, morphology, properties and applications. Compos, Part A: Appl Sci Manuf 2007;38:1694–709. [56] Food and agriculture organization of the United Nations. Agricultural price statistics; 2010 [upated 10.09.10; accesed 15.11.10]. . [57] Van de Velde K, Kiekens P. Biopolymers: overview of several properties and consequences on their applications. Polym Test 2002;21:433–42. [58] Averous L, Moro L, Dole P, Fringant C. Properties of thermoplastic blends: starch-polycaprolactone. Polymer 2000;41:4157–67. [59] Clarinval AM. Classification and comparison of thermal and mechanical properties of commercialized polymers. In: IENICA, editor. International congress & trade show, industrial applications of bioplastics. York, UK; 2002, February 3–5. [60] Tsuji H. In vitro hydrolysis of blends from enantiomeric poly(lactide)s Part 1. Wellstereo-complexed blend and non-blended films. Polymer 2000;41:3621–30. [61] Phong L, Han ESC, Xiong S, Pan J, Loo SCJ. Properties and hydrolysis of PLGA and PLLA cross-linked with electron beam radiation. Polym Degrad Stab 2010;95:771–7. [62] Ahankari SS, Mohanty AK, Misra M. Mechanical behaviour of agro-residue reinforced poly(3-hydroxybutyrate-co-3-hydroxyvalerate), (PHBV) green composites: A comparison with traditional polypropylene composites. Compos Sci Technol 2011;71:653–7. [63] Li Y, Shimizu H. Improvement in toughness of poly(l-lactide) (PLLA) through reactive blending with acrylonitrile-butadiene-styrene copolymer (ABS): morphology and properties. Eur Polym J 2009;45:738–46. [64] Curvelo AAS, de Carvalho AJF, Agnelli JAM. Thermoplastic starch-cellulosic fibers composites: preliminary results. Carbohydr Polym 2001;45:183–8. [65] Shiroma E, Drumond S, Blazek G, Souza MR, Lachtermacher M, Wang SH. PHB toughening by blending with polyethyl glycol. In: World polymer congress and 41st international symposium on macromolecules. Brasil: Rio de Janeiro; 2006. p. 1–2 [July 16–21]. [66] Dent A, H. Breakdown: Biodegradable Plastics. MATTER Magazine; 2008;5(2) [cited 05.09.11]. . [67] Vilaseca F, Mendez J, Pelach A, Llop M, Canigueral N, Girones J, et al. Composite materials derived from biodegradable starch polymer and jute strands. Process Biochem 2007;42:329–34. [68] Bodros E, Pillin I, Montrelay N, Baley C. Could biopolymers reinforced by randomly scattered flax fibre be used in structural applications? Compos Sci Technol 2007;67:462–70.

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