Diels-Alder is also called a [4+2] cycloaddition because a ring is formed by the interaction of four pi electrons of the alkene with two pi electrons of the alkene or alkyne. The product of the Diels-Alder reaction is usually a structure that contains a cyclohexene ring system. The mechanism of the reaction involves a cyclic flow of electrons in a single step in which the diene‚ supplies 4 π electrons and the alkene or alkyne‚ also called the dienophile‚ supplies 2 π electrons. In this process‚ two new
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Analysis of Hydrocarbons Jessa Grace B. Castillo* and Stephanie Chua Department of Chemistry‚ University of Santo Tomas‚ Manila‚ Philippines ______________________________________________ Hydrocarbons are organic compounds containing only hydrogen and carbons and further divided in major types. Hydrocarbons react differently in reagents. The basis of determining an unknown hydrocarbon is due to the differences in reactions of hydrocarbons. An unknown compound is determined using tests.
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4-methylcyclohexene‚ and trace acid. D. Questions: 1. Outline a mechanism for the dehydration of 4-methylcyclohexanol catalyzed by phosphoric acid. 2. What major alkene product is produced by the dehydration of the following alcohols? a. Cyclohexanol Cyclohexene b. 1-Methylcyclohexanol methylcyclohexene c. 2-Methylcyclohexanol methylcyclohexne d. 2‚2-dimethylcyclohexanol 1‚2-dimethylcyclohexene 3. Compare and interpret the infrared spectra of 4-Methylcyclohexene and 4-Methylcyclohexanol. 4. Identify
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Equations: Theoretical Yield: There was no Theoretical yield in this experiment Procedure: Fill a 50 mL beaker with 30 mL of water and place it on the hot plate. Add 14 drops of olive oil to a 10 mL round bottom flask and then add 1 mL of cyclohexene. Add .05 grams of 10% palladium-on-carbon to the round bottom flask. Add a boiling chip to the round bottom flask and attach the flask to your reflux condenser. Use the water bath from the first step to reflux the mixture for approximately 20 minutes
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Keghan Chapter 8 MULTIPLE CHOICE QUESTIONS Topic: Structure Elucidation 1. An alkene adds hydrogen in the presence of a catalyst to give 3‚4-dimethylhexane. Ozonolysis of the alkene followed by treatment with zinc and acetic acid gives a single organic product. The structure of the alkene is: CH3 A) CH3CH=C-CHCH2CH3 (cis or trans) CH3 CH3 B) CH3CH2C=CCH3 (cis or trans) CH2CH3 C) CH3 CH2=CCH2CHCH2CH3 CH3 CH2 D) CH3CH2CCHCH2CH3 CH3 CH3 E) CH3CH2CHCHCH=CH2
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Limiting Reagents and Percentage Yield Worksheet 1. Consider the reaction I2O5(g) + 5 CO(g) -------> 5 CO2(g) + I2(g) a) 80.0 grams of iodine(V) oxide‚ I2O5‚ reacts with 28.0 grams of carbon monoxide‚ CO. Determine the mass of iodine I2‚ which could be produced? 80 g I2O5 1 mol I2O5 1 mol I2 1 333.8 g I2O5 1 mol I2O5 28 g CO 1 mol CO 1 mol I2 253.8 g I2 1 28 g CO 5 mol CO 1 mol I2 b) If‚ in the above situation‚ only 0.160 moles‚ of iodine‚ I2 was produced
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FOUNDATION IN SCIENCE INTRODUCTION TO PRACTICAL ORGANIC CHEMISTRY – MAKING AND PURIFYING ORGANIC COMPOUNDS Stage 1 – Deciding how much reagent to use Most organic reactions do not go to completion; most reach an equilibrium position with significant quantities of reactants still remaining. In addition‚ separating the desired product from the rest of the reaction mixture‚ and then purifying it‚ will result in the loss of more of the product. The amount of product obtained expressed as a percentage
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Alkane‚ Alkene‚ Alkyne & Aromatic Learning Objectives 1. 2. 3. Determine the IUPAC name‚ common name and structure of an alkanes‚ alkenes and cycloalkanes. Identify the physical properties of alkanes. Describe briefly natural sources and importance of alkanes Describe reactions of alkanes Propose a mechanism on free radicals substitution 4. 5. 6. Describe the preparation and reactions of alkenes. 7. Propose mechanism on preparation; dehydration of alcohol 8. Define carbocation
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H.B Fuller and the Street Children Of Central America (Honduras) Introduction Background of the case is the misuse one of the adhesives‚ Resistol‚ a toluene base glue‚ by the street o children of america‚ where the social economic were taken part of this situation. The resistol were produced by H.B Fuller company‚a global manufacture of adhesives‚ selalants‚ and other specialty chemicals‚ and had operations in over 40 countries in North America‚ Europe‚ Asia and Latin America. H.B Fuller 1994 total
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Paul Hermann Diels and Kurt Alder first documented this type of reaction‚ hence the name Diels-Alder reactions. Their reaction is one of the more useful reactions done in chemistry because it does not require very much energy in order to make the cyclohexene ring and the result can create four stereo centers‚ making it compatible for a variety of functional groups which still has double bonds in the products. Dimethyl Tetraphenylphthalate. Tetraphenylcyclopentadienone (0.100g)‚ dimethyl acetylene-dicarboxylate
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