Metallic bonding: Found in metals and alloys, 1, 2, or 3 valence electrons that are not bound to any particular atom in the solid. They drift throughout the entire metal. This results in a sea of electrons. These free electrons result in good electrical and heat conductivity. Coordination number is 8 or 12 (number of nearest neighbors). Ionic Bonding
Found in compounds that are composed of both metallic and nonmetallic elements. Metallic element gives up valence electrons to the nonmetallic elements. Attractive forces from positive and negative ions
Ceramic materials: high melting temperatures, hard, poor conductors Covalent Bonding
Electrons are shared between adjacent atoms resulting in stable electron configurations. Many nonmetallic elemental molecules are covalently bonded. Polymeric materials have this bond. Crystal Structure
Describe the crystal structure using an array of points or lattice. The unit cell is the smallest number of atoms that describes the crystal structure. FCC: aluminum, copper, gold, lead, nickel, silver.
Coordination number, number of nearest neighbors is 12.
Atomic Packing Factor
APF = volume of atoms in a unit cell
Total unit cell volume
Crystallographic Planes and Directions
Crystallographic Directions: a vector with coordinates in the xyz axis system. The length of the vector is the smallest integer values. They are written [uvw] i.e.  This defines a direction. Crystallographic Planes: Miller indicies are (hkl). Three numbers that define the orientation of a plane with respect to a given coordinate system.
h = a/x
k = a/y
l = a/z
Defining a Plane
The plane cannot go through the origin of the cell.
The plane either intersects or parallels each of the three axes. The length of the planar intercept for each axis is determined in terms of the lattice parameters a,b,c The reciprocals of these numbers are taken. A plane that parallels an axis may be considered to have an infinite intercept, and a zero index. These numbers are changed to the set of smallest integers.
The integer indices, not separated by commas, are enclosed within parentheses. Dislocations
Edge dislocations, Screw dislocations.
Dislocation movement and how this effects mechanical properties. Phase Diagrams
Determine phases present.
Determine amount of each phase.
Determine composition of each phase.
Continuous Cooling Curves.
Time Temperature Transformations.
Non Equilibrium phases.
Stress = Load /Area
Strain = Change in length / initial length
Modulus = Stress / Strain
Tensile deformation of ductile metal
Ductile vs. brittle
Stress Strain Curve
Ultimate Tensile Strength
Modulus of Elasticity
Would you expect MgO or magnesium to have a higher modulus of elasticity? Dislocations
Extra half plane
Perpendicular to edge dislocation
Parallel to screw dislocation
Strength is inversely related to dislocation mobility.
Crystal structure determines the number and type of slip systems. Grain size determines the amount of grain boundary area and thus dislocation mobility. Finer grain size results in higher strength.
Grain Boundary Strengthening
Hall – Petch Relationship
Stress = Friction stress + constant/(grain diameter)1/2
Friction Stress = stress to move unlocked dislocation along slip plane This says the smaller the grain size, the higher the strength. This is true if comparing two annealed materials with different grain size. If cold work is present, this can alter relationship.
Number of grains per square inch @ 100X = N.
Grain size number = n
N = 2 (n-1)
The smaller the grain size, the larger the grain size number. Yield-Point Phenomenon
Upper and lower yield point occurs in low-carbon steel.
This results in luders bands or stretcher...
Please join StudyMode to read the full document