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    Friedel-Crafts Reactions

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    electrophilic aromatic substitutions which result in the formation of new carbon-carbon bonds are called ‘Friedel-Crafts’ alkylations and acylations‚ named for Charles Friedel of France and James Crafts of the United States‚ who together developed the procedures in 1877. The Friedel-Crafts reactions are an important part of a synthetic chemist’s toolbox to this day. Friedel Crafts reactions‚ like their biochemical counterparts‚ require reactive electrophiles with significant carbocation character

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    Friedel Crafts Alkylation

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    9/17/2014-9/24/2014 Lab Partner: Erika Breeden Synthesis of 1‚4-Di-t-Buytl-2‚5-Dimethoxybenzene via Friedel-Crafts Alkylation Title: Synthesis of 1‚4-Di-t-buytl-2‚5-dimethoxybenzene via Friedel-Crafts Alkylation Introduction: Friedel-Crafts alkylation of benzene (and substituted benzenes) involves substituting a hydrogen atom on a benzene ring with an alkyl group. In the reaction a new alkyl group becomes bonded to a carbon atom of the aromatic ring which occurs by treatment of benzene

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    Friedel-Crafts Alkylation Reaction Friedel-Crafts Alkylation Reaction Preparation of 1‚ 4-Di-t-butyl-2‚ 5-dimethoxybenzene Microscale Experiment Leah Monroe April 8‚ 2003 Organic Chemistry Lab II Experiment performed on March 20 and 25‚ 2003 Lab Partners (NMR only): Shannon Land and Jamie Yeadon Abstract: In this experiment‚ 1‚4-dimethoxybenzene reacted with t-butyl alcohol to form 1‚ 4-Di-t-butyl-2‚ 5 – dimethoxybenzene via a Friedel-Crafts Alkylation mechanism. A small amount of 1‚4-dimethoxybenzene

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    THE FRIEDEL-CRAFTS REACTION: ACETYLATION OF FERROCENE Ferrocene was acetylated in acetic anhydride and phosphoric acid. It proceeded via a Friedel-Crafts reaction without the use of organic solvents or strong Lewis acid. Operations and Observations A mixture of ferrocene (1.5 g‚ 0.008 mol)‚ acetic anhydride (5 mL) and phosphoric acid (1 mL 85%) was heated over a steam bath until all the ferrocene dissolved and the mixture darkened from orange to dark red. The mixture was then refluxed with

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    Lab Report 1 Friedel-Crafts Alkylation of Benzene and Dimethoxybenzene Objective: 1. To understand the general process‚ reaction and limitations of Friedel-Crafts Alkylation in regards to Dimethoxybenzene 2. To apply the reaction of Friedel-Crafts Alkylation to dimethoxybenzene Chemical Index: Chemical Structure Molecular Weight Melting Point Boiling Point Acetic Acid C2H4O2 60.05 g/mol 16-17°C 118-119°C T-Butanol C4H10O

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    Introduction Friedel-Crafts acylation of anisole with acetic anhydride was used in this experiement to synthesize 4-methoxyacetophenone with the use of a reflux apparatus. Friedel-Crafts reactions can be done by alkylation‚ which involves mixing an alkyl or acyl halide with a Lewis acid‚ or acylation‚ which is done with acid chlorides or anhydrides(Lefevre). Acylation was used because it does not have as many disadvantages aklyations reactions have such as polyalkylation‚ second electrophilic attacks

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    Jessica Zebracki Organic Chem II Lab 2/15/15 Friedel-Crafts Acylation of Ferrocene and Column Chromatography Introduction: The intention of this lab is to analyze the formation of acetylferrocene using column chromatography. The Friedel-Crafts acylation reaction created acetylferrocene and diacetylferrocene‚ using phosphoric acid as a catalyst for the reaction between acetic anhydride and ferrocene (once applying heat). During column chromatography‚ a solution is passed through a filtration system

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    Friedel Crafts Alkylation Reaction Introduction: In the experiment we will create 1‚4-Di-t-Butyl-2‚5-Dimethoxybenzene by performing a Friedel-Crafts reaction on 1‚4-Dimethoxybenzene. In the reaction a t-butyl carbocation will be added on to the 1‚4-Dimethoxybenzene. The t-butyl carbocation will be formed by a reaction of t-butyl alcohol with sulfuric acid. To perform the reaction we will create a mixture of the 1‚4-Dimethoxybenzene‚ t-butyl alcohol with acetic acid. To this mixture we will

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    Desi Crafts

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    Desi Crafts | Creativity‚ Excellence‚ Touch of Tradition | A local Handicrafts selling business | | Submitted By-Fahmina HuqID- 1111382030Course- BUS251Section- 7 | | | | * Letter of Transmittal August 2‚ 2012 Taufique Hossain‚ Instructor of BUS 251‚ BBA Dept. North South University Dear Sir‚ In this report I have tried to do the analysis with due sincerity and I would like to thank you for giving us the opportunity to have the chance to work on this. Despite

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    Arts and Craft

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    Arts and Crafts Origins and key principles The Arts and Crafts movement was a British and American aesthetic movement occurring in the last years of the 19th century and the early years of the 20th century. Inspired by the writings of John Ruskin and a romantic idealization of the craftsman taking pride in his personal handiwork‚ it was at its height between approximately 1880 and 1910. It was a reformist movement that in uenced British and American architecture‚ decorative arts‚ cabinet making

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