Experiment N | Kinetics of the Depolymerization of Diacetone Alcohol via Basic Catalysis | | Ingrid Tafur -5672578 | 2/11/2011 | CHM233O Partner: Laura Marrongelli Demonstrator: Cheryl McDowall Objective The rate constant of the depolymerization of diacetone alcohol via basic catalysis was determined by monitoring the change in volume as a function of time at constant temperature of a pseudo first order reaction where the species in excess was sodium hydroxide. This was accomplished
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Chemistry 2740 Laboratory Experiment 2 A KINETIC STUDY OF THE BASE CATALYZED CLEAVAGE OF DIACETONE ALCOHOL USING A DILATOMETER The decomposition of diacetone alcohol into two molecules of acetone is catalyzed by hydroxide ions and is an example of an aldol condensation in reverse. O OH OHO 2CH3-C-CH3 CH3-C-CH2-C(CH3)2 The rate of decomposition is first-order with respect to the concentrations of both diacetone alcohol and hydroxide ion: Rate = k[OH-][diacetone alcohol] (1) However‚ since
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Catalysis: Midterm Review LECTURE 1: Sept 6th 2012 What is catalysis‚ Importance of catalysis‚ Industrial relevance‚ presentation of the course What is Catalysis: Catalyst: * catalyst is substance that increases the rate at which a chemical reaction approaches equilibrium‚ but is not consumed in the process * not reagent or product; noted above equation arrow * participates in kinetic equations‚ but not in eq constant Catalytic Cycle: * succession of chemical changes
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Experiment #7 Fall 2014 Dehydration of an alcohol NAME Nick Weinberger POSTLAB 1. Show the mechanism for the dehydration of -tetralol under conditions employed in the lab. Show all intermediates‚ and show electron flow with arrows. 2. What general mechanism most likely applies to this reaction (SN2‚ E2 etc)? E1 3. Why was acid employed in this reaction? The acid was used to protonate the leaving group (OH) to form water which is a much better leaving
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Experiment 16: Kinetics: The Iodine Clock Jane Smith Purpose: The objective of this experiment was for students to apply their knowledge of kinetics and rate laws in order to determine the rate of a chemical reactions‚ activation energy‚ and frequency factors of those reactions. Specifically‚ this experiment was performed using a series of solutions with varying concentrations of KI‚ Na2S2O3‚ and (NH4)2S2O3 . Students recorded time elapsed to observe physical evidence of a reaction taking place
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not healthy. The problem of alcohol and drug abuse is of central concern nowadays. It is especially acute among the youth and this fact horrifies most of all. Today the statistics shows deplorable numbers of young people‚ drinking and taking drugs. Alcohol abuse is itself very harmful for a human organism‚ especially for a young one as it destroys brain cells and other organs. However‚ the harmful effect on different apparatuses is not the only harm brought by alcohol abuse. The consequences of alcoholic
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HETEROGENEOUS CATALYSIS D. C. AGUILAR AND B. N. SANCHEZ INSTITUTE OF CHEMISTRY‚ COLLEGE OF SCIENCE UNIVERSITY OF THE PHILIPPINES‚ DILIMAN QUEZON CITY‚ PHILIPPINES RECEIVED MARCH 17‚ 2008 ABSTRACT Catalysis which involves the use of a catalyst in a different phase from the reactants is known as heterogeneous catalysis. Catalysts are known to enhance rates of reaction without being consumed and they also reduce activation energies. The hydrogen peroxide decomposition reaction catalyzed
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Enzyme Catalysis Abstract: Catalysis is an enzyme that decomposes hydrogen peroxide into oxygen and water. In this lab we will conduct a series of experiments to determine the affects of; pH‚ temperature‚ and concentration change on such catalysis. After completing the experiments we determined that catalase works most efficiently when in a 27°c‚ 50% (5 ml of catalase – 5ml of water)‚ and a normal body pH of 7°. By: Patrick Jawien Course Code: SBI 4U Performance Date: 25 September 2012
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Enzyme kinetics (catalase/kmno4) Enzyme catalysis Farah Mohamed galal 22-3014 t09 Introduction: E + S → ES → E + P Enzymes are proteins which act as a catalyst in biochemical reactions(affect the rate of achemical reaction). The substrate binds to the active site of the enzyme. Any deformation of the active site will affect the activity of the enzyme‚ these are some ways that enzyme action may be affected because of them: 1- Salt concentration: If it is close to zero or very high
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A KINETIC STUDY OF AN IODINE CLOCK REACTION PURPOSE To investigate the kinetics of the reaction that occurs between iodide and persulfate ion. You will: (1) determine the rate law‚ (2) determine the numerical value of the rate constant at room temperature‚ (3) explore the effect of temperature on the reaction and determine the activation energy (Ea)‚ and (4) investigate catalytic activity of selected metal ions on the reaction. INTRODUCTION Reaction times vary from picoseconds (10-12 seconds)
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