purpose of this experiment was to identify one ketone with Thin Layer Chromatography and one using NMR spectrometry. We will do this by making 2‚ 4 a DNPH derivative and checking the melting points. Theory: By Using specific methods of compounds detection‚ we can match an unknown compound with a known compound because similar compounds will display similar characteristics. In this experiment‚ identifications of the unknown ketone was accomplished using thin layer chromatography‚ melting point
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Laboratory #6 Qualitative Tests for Carbonyls: Aldehydes vs. Ketones Introduction Various chemical tests identifying ketones and aldehydes are used in this experiment in order to identify an unknown carbonyl compound. The tests used are: 2‚4-dinitrophenylhydrazone test‚ Tollen’s Test‚ Benedict’s Test‚ Chromic Acid Test‚ aka Bordwell-Wellman Test‚ Schiff’s Test‚ and Iodoform Test. These classification tests provide results based on color change or formation of precipitation‚ which is then used
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Aldol Condensation Wei-Hsuan Tsui 4/16/14 The reaction of an aldehyde with a ketone employing sodium hydroxide as the base is an example of a mixed aldol condensation reaction‚ the Claisen-Schmidt reaction. Dibenzalacetone is readily prepared by condensation of acetone with two equivalents of benzaldehyde -26 -95 113.9 1. Weigh 0.212 g of pure benzaldehyde directly into a 10 x 100 mm reaction tube. 2.
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Aldol In this preparative lab‚ an aldol (trans-p-anisalacetophenone) was produced from the reaction between p-anisaldehyde and acetophenone with the presence sodium hydroxide. The reaction also showed the importance of an enolate and the role it played in the mechanism. Sodium hydroxide acts as a catalyst in this experiment and is chosen because of its basic conditions and pH. The acetophenone carries an alpha hydrogen that has a pKa between 18 and 20. This alpha hydrogen is acidic because of its
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Aldol Condensation: Synthesis of Dibenzalacetone Aldol Condensation: Synthesis of Dibenzalacetone Leah Monroe May 15‚ 2003 Organic Chemistry Lab II Experiment performed on May 6 and 8‚ 2003 Abstract: The purpose of this experiment was to synthesize dibenzalacetone via an aldol condensation reaction between acetone and benzaldehyde. This was done by mixing the two reactants with NaOH and ethanol‚ then allowing the reaction to sit for thirty minutes. The crystals were then washed with
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Report Aldol Reaction Purpose: The purpose of this experiment is to be able to conduct an aldol condensation reaction using an unknown aldehyde and an unknown ketone. H NMR is used to identify the unknown aldehyde and ketone. Melting point is used to identify the aldol condensation reaction. Theory: Condensation reaction is also known as a dehydration reaction. In the mechanism of condensation reaction‚ a bond is formed between two molecules and creates water as a byproduct. Aldol condensation
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The goal of this experiment was to synthesize dibenzalacetone by aldol synthesis. The name ’Aldol synthesis’ was taken from the words ’aldehyde and alcohol’. This is because the product of this reaction contains both an aldehyde and alcohol. The carbon-carbon bond-forming reaction is referred to as aldol addition. An aldol condensation yields many species of products if the reactant is more than one. Therefore‚ the aldehyde has to react with itself to yield one product. Procedure: Followed according
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1)With 1-mL graduated pipet‚ measure 0.40 mL of the unknown labled “no.XX-.40 mL 2) With another 1ml graduated pipet measure 0.10 Ml of the unknown labled “no. XX- 0.10 mL” 3) Add the compounds to the same Erlenmeyer flask 4) Add 2.0 mL of 95% ethanol and 1.5 mL of 2 M sodium hydroxide solution to the flask 5)Stir with magnetic stirrer for 15 minutes or longer if precipitate still forming (if cloudy after 15 mina heat mixture on a asteam bath or in boiling water for 10 mins then cool
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Aldol Condensation Discussion: 1. Aldol condensation reactions take place in basic conditions‚ where a deprotonated enol becomes an enolate and proceeds to attack the aldehyde. Since the solution is basic‚ it is able to deprotonate the alpha carbons of the product‚ which forces the hydroxide groups to leave. The product is then considered to be dehydrated and unsaturated. In terms of our reaction‚ cyclopentatone is deprotonated to form an enolate‚ which then attacks the two molecules of p-tolualdehyde
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Objective: The benefit of this lab was to acquaint oneself with the fundamentals of the Aldol Condensation reaction by demonstrating the synthesis of dibenzalacetone (trans‚ trans-1‚5-Diphenyl-1‚4-pentadien-3-one) through the aldol condensation of acetone with benzaldehyde. The synthesis began by using a strong base to generate the acetone enolate ion. The ketone/enol tautomerization is an equilibrium process that produces little of the enol (ppm or less). However‚ any enol that formed quickly reacted
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