The purpose of this experiment was to perform a wittig reaction‚ the horner-emmons wittig specifically‚ reacting an aldehyde with an ylide to make an alkene. This particular variation of the wittig reaction has several advantages: It gives only the trans product; it uses a much milder base that is easier to handle; and it gives a water soluble byproduct which is easy to separate from the product. The reason that these advantages occur is a change in the structure of the ylide. Instead of a tripheylphosphine
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Chemistry 3373F Lab Manual 2008 Modified 11/07 Table of Contents Chem 3373 Laboratory Schedule for Fall 2008.............................................................................2 The Benzoin Condensation of Benzaldehyde ..............................................................................3 Synthesis of Dilantin and Related Compounds (two weeks).........................................................6 Synthesis of an Alkaloid: Pseudopelletierine (two weeks) .............
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mentioned unstable equilibrium‚ while nucleophile OH- in equation (iii) is much higher1. When the OH- reacts with alkyl halide (iii) or acyl halide (iv)‚ the conjugate base will tend to react with the unreacted carbonyl compound by means of an aldol condensation reaction as shown in equation (vi)1. Results Preparation of the enamine Pyrrolidine Cyclohexanone Molecular formula: C4H9N Molecular formula: C6H10O Volume: 4.0 ml +. Volume: 5.0 ml Density: 0.87 g cm-3 Density:
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2740 Laboratory Experiment 2 A KINETIC STUDY OF THE BASE CATALYZED CLEAVAGE OF DIACETONE ALCOHOL USING A DILATOMETER The decomposition of diacetone alcohol into two molecules of acetone is catalyzed by hydroxide ions and is an example of an aldol condensation in reverse. O OH OHO 2CH3-C-CH3 CH3-C-CH2-C(CH3)2 The rate of decomposition is first-order with respect to the concentrations of both diacetone alcohol and hydroxide ion: Rate = k[OH-][diacetone alcohol] (1) However‚ since hydroxide
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Citric acid cycle From Wikipedia‚ the free encyclopedia Jump to: navigation‚ search [pic] [pic] Overview of the citric acid cycle The citric acid cycle — also known as the tricarboxylic acid cycle (TCA cycle)‚ the Krebs cycle‚ or the Szent-Györgyi-Krebs cycle‚ [1][2] — is a series of enzyme-catalysed chemical reactions‚ which is of central importance in all living cells that use oxygen as part of cellular respiration. In eukaryotic cells‚ the citric acid cycle occurs in the matrix of the mitochondrion
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UPSEE - 2009 Full Paper Section-1 Physics 1. If 3.8 × 10-6 is added to 4.2 × 10-5 giving due regard to significant figures‚ then the result will be : 1) 4.58 × 10-5 2) 4.6 × 10-5 3) 4.5 × 10-5 4) None of these 2. A ball is dropped from a bridge at a height of 176.4 m over a river. After 2 s‚ a second ball is thrown straight downwards. What should be the initial velocity of the second ball so that both hit the water simultaneously ? 1) 2.45 ms-1 2) 49 ms-1 3) 14.5 ms-1 4) 24.5 ms-1 3. Which of the
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ACKNOWLEDGEMENT The success of this investigatory project is directly related to the contributions of the ever supportive persons in my aura: To my friends who were there to cheer me up in time of doing this investigatory project‚ “Thank you so much!” To my parents who help me in providing significant material contributions‚ “Thank you and I love you so much!” To my adviser‚ Analiza R. Barcarse for her exquisite attention in guiding me‚ “Thank you‚ Ma’am!” To Ms. Estrella B. Acosta‚ the Science
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Chapter 1 MULTIPLE CHOICE QUESTIONS Topic: Atomic Orbitals 1. A) B) C) D) E) In quantum mechanics a node (nodal surface or plane) is: a place where Ψ is negative. a place where Ψ is positive. a place where Ψ = 0. a place where Ψ2 is large. a place where Ψ2 is negative. Ans: C Topic: Atomic Orbitals‚ Molecular Orbitals 2. When the 1s orbitals of two hydrogen atoms combine to form a hydrogen molecule‚ how many molecular orbitals are formed? A) 1 B) 2 C) 3 D) 4 E) 5 Ans:
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3090 3090▌ SHORT REVIEW Reaction of Diazo Compounds with Organoboron Compounds short review Huan Li‚ Yan Zhang‚ Jianbo Wang* Reaction of Diazo Compounds with Organoboron Compounds Abstract: The transition-metal-free reactions of diazo compounds with organoboron compounds are reviewed. This type of reaction provides an alternative approach for the formation of C–C‚ C–B‚ and C–Si bonds. Moreover‚ by using tosylhydrazones as diazo compound precursors and boronic acids/esters as the
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CHEMISTRY OF NATURAL PRODUCTS Terpenoids Sameena Bano Department of Chemistry Faculty of Science Jamia Hamdard New Delhi-110062 (24.09.2007) CONTENTS Introduction Classification of Terpenoids Isolation of mono and sesquiterpenoids General properties of Terpenoids General methods of structure elucidation Terpenoids Citral Menthol Camphor Eugenol Keywords Terpenes‚ isoprene‚ citral‚ menthol‚ camphor and eugenol 1 Introduction There are many different classes of naturally occurring
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