Thermochemistry

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Thermochemistry

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Thermochemistry is the study of the heat released or absorbed as a result of chemical reactions. It is a branch of thermodynamics and is utilized by a wide range of scientists and engineers. For example, biochemists use thermochemistry to understand bioenergetics, whereas chemical engineers apply thermochemistry to design manufacturing plants. Chemical reactions involve the conversion of a set of substances collectively referred to as "reactants" to a set of substances collectively referred to as "products." In the following balanced chemical reaction the reactants are gaseous methane, CH 4 (g), and gaseous molecular oxygen, O 2 (g), and the products are gaseous carbon dioxide, CO 2 (g), and liquid water H 2 O(l):

CH 4 (g) + 2 O 2 (g) → CO 2 (g) + 2 H 2 O(l) (1)

Reactions in which a fuel combines with oxygen to produce water and carbon dioxide are called combustion reactions. Because natural gas consists primarily of methane, it is expected that reaction (1) will liberate heat. Reactions that liberate heat are termed exothermic reactions, and reactions that absorb heat are termed endothermic reactions.

The heat associated with a chemical reaction depends on the pressure and temperature at which the reaction is carried out. All thermochemical data presented here are for reactions carried out under standard conditions, which are a temperature of 298 K (24.85°C) and an applied pressure of one bar . The quantity of heat released in a reaction depends on the amount of material undergoing reaction. The chemical formulas that appear in a reaction each represent 1 mole (see article on "Mole Concept") of material; for example, the symbol CH 4 stands for 1 mole of methane having a mass of 16 grams (0.56 ounces), and the 2 O 2 (g) tells us that 2 moles of oxygen are required. Thermochemistry also depends on the physical state of the reactants and products. For example, the heat liberated in equation (1) is...
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