Heat Transfer Lab Manual

Topics: Heat, Heat transfer, Thermodynamics Pages: 32 (4896 words) Published: February 7, 2013

(MEC 2700)


JULY 2007

Table of Contents
Experiment 1: Heat Capacity of Gases
Experiment 2: Thermal and Electrical Conductivity of Metals Experiment 3: Heat Pump
Experiment 4: Heat Conduction
Experiment 5: Free and Forced Convection
Experiment 6: Thermal Radiation

Experiment 1: Heat Capacity of Gases


The first law of thermodynamics can be illustrated particularly well with an ideal gas. This law describes the relationship between the change in internal intrinsic energy ΔUi the heat exchanged with the surroundings ΔQ and the constant-pressure change pdV.

dQ = dUi + pdV (1)

The molar heat capacity C of a substance results from the amount of absorbed heat and the temperature change per mole:


n = number of moles

One differentiates between the molar heat capacity at constant volume CV and the molar heat capacity at constant pressure Cp.

According to equations (1) and (2) and under isochoric conditions (V const., dV = 0), the following is true:


and under isobaric conditions (p = const., dp = 0):


Taking the equation of state for ideal gases into consideration:

pV = n R T (5)

it follows that the difference between Cp and CV for ideal gases is equal to the universal gas constant R.

Cp – CV = R (6)

It is obvious from equation (3) that the molar heat capacity CV is a function of the internal intrinsic energy of the gas. The internal energy can be calculated with the aid of the kinetic gas theory from the number of degrees of freedom f:


kB = 1.38 · 10-23 J/K (Boltzmann Constant)

NA = 6.02 · 1023 mol-1 (Avogadro's number)

Through substitution of

R = kB NA (8)

it follows that


and taking equation (6) into consideration:


The number of degrees of freedom of a molecule is a function of its structure. All particles have 3 degrees of translational freedom. Diatomic molecules have an additional two degrees of rotational freedom around the principal axes of inertia. Triatomic molecules have three degrees of rotational freedom. Air consists primarily of oxygen (approximately 20%) and nitrogen (circa 80%). As a first approximation, the following can be assumed to be true for air:

f = 5

CV = 2.5 R

CV = 20.8 J · K-1 · mol-1


Cp = 3.5 R

Cp = 29.1 J · K-1 · mol-1.


The experiment aims to determine the molar heat capacities of air at constant volume Cv and at constant pressure Cp.


Precision manometer
Digital counter
Digital multimeter
Aspirator bottle (10000 ml)
Gas syringe (100 ml)
Stopcock, 1-way and 3-way
Rubber stopper, d = 32/26 mm, 3 holes
Rubber stopper, d = 59.5/50.5 mm, 1 hole
Rubber tubing, d = 6 mm
Nickel electrode
Chrome-nickel wire
Push-button switch


Part A – Determining the Constant Value Cv

i) The setup is as shown in Figure 1.
ii) To determine Cv, connect the precision manometer to the bottle with a piece of tubing. The manometer should be positioned exactly horizontally. Pressure increase has to be read immediately after the heating process. iii) Begin the measuring procedure by pressing the push button switch. The measuring period should be less than a second. iv) Take readings of the pressure (from the manometer), the current and voltage. v) Remove the air from the aspirator bottle after each measurement. vi) Repeat steps iii) to v) in order to obtain 10 sets of results. Vary Δt within the given range.

Part B – Determining the Constant Value Cp

i) The setup is as shown in Figure 2.
ii) Replace the precision manometer with two...
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