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conduction
The fundamental modes of heat transfer are:
Conduction or diffusion
The transfer of energy between objects that are in physical contact
Convection
The transfer of energy between an object and its environment, due to fluid motion
Radiation
The transfer of energy to or from a body by means of the emission or absorption of electromagnetic radiation
Mass transfer
The transfer of energy from one location to another as a side effect of physically moving an object containing that energy
Conduction

On a microscopic scale, heat conduction occurs as hot, rapidly moving or vibrating atoms and molecules interact with neighboring atoms and molecules, transferring some of their energy (heat) to these neighboring particles. In other words, heat is transferred by conduction when adjacent atoms vibrate against one another, or as electrons move from one atom to another. Conduction is the most significant means of heat transfer within a solid or between solid objects in thermal contact. Fluids—especially gases—are less conductive. Thermal contact conductance is the study of heat conduction between solid bodies in contact.
Steady state conduction is a form of conduction that happens when the temperature difference driving the conduction is constant, so that after an equilibration time, the spatial distribution of temperatures in the conducting object does not change any further. In steady state conduction, the amount of heat entering a section is equal to amount of heat coming out.
Transient conduction occurs when the temperature within an object changes as a function of time. Analysis of transient systems is more complex and often calls for the application of approximation theories or numerical analysis by computer.

Convection
Main article: Convective heat transfer
Convective heat transfer, or convection, is the transfer of heat from one place to another by the movement of fluids. (In physics, the term fluid means any substance that deforms under shear stress; it includes liquids, gases, plasmas, and some plastic solids.) Bulk motion of the fluid enhances the heat transfer between the solid surface and the fluid.[3] Convection is usually the dominant form of heat transfer in liquids and gases. Although often discussed as a third method of heat transfer, convection actually describes the combined effects of conduction and fluid flow.
Free, or natural, convection occurs when the fluid motion is caused by buoyancy forces that result from density variations due to variations of temperature in the fluid. Forced convection is when the fluid is forced to flow over the surface by external means—such as fans, stirrers, and pumps—creating an artificially induced convection current.[4]
Convection is described by Newton's law of cooling: "The rate of heat loss of a body is proportional to the difference in temperatures between the body and its surroundings."

Thermal radiation is the transfer of heat energy through empty space by means of electromagnetic waves. All objects with a temperature above absolute zero radiate energy. No medium is necessary for radiation to occur, for it is transferred by electromagnetic waves; radiation takes place even in, and through, a perfect vacuum. For instance, the energy from the Sun travels through the vacuum of space before warming the Earth. Radiation is the only form of heat transfer that can occur in the absence of any form of medium (i.e., through a vacuum).
Thermal radiation is a direct result of the movements of atoms and molecules in a material. Since these atoms and molecules are composed of charged particles (protons and electrons), their movement results in the emission of electromagnetic radiation, which carries energy away from the surface. At the same time, the surface is constantly bombarded by radiation from the surroundings, resulting in the transfer of energy to the surface. Since the amount of emitted radiation increases with increasing temperature, a net transfer of energy from higher temperatures to lower temperatures results.
Unlike conductive and convective forms of heat transfer, thermal radiation can be concentrated in a tiny spot by using reflecting mirrors. Concentrating solar power takes advantage of this fact. For example, the sunlight reflected from mirrors heats the PS10 solar power tower, and during the day it can heat water to 285 °C (545 °F).
[edit]Mass Transfer
In mass transfer, energy—including thermal energy—is moved by the physical transfer of a hot or cold object from one place to another. This can be as simple as placing hot water in a bottle and heating a bed, or the movement of an iceberg in changing ocean currents. A practical example is thermal hydraulics.
[edit]Convection vs. conduction
In a body of fluid where heat enters at its lower end and leaves at its upper end, conduction and convection can be considered to "compete" for dominance (ignoring any radiation). If heat conduction is too great, fluid moving down by convection will be heated by conduction so fast that its downward movement will be stopped due to its buoyancy, while fluid moving up by convection will be cooled by conduction so fast that its driving buoyancy will diminish. On the other hand, if heat conduction is very low, a large temperature gradient will be formed and convection will be very strong.

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