Diels-Alder Reaction: Synthesis of cis-Norbornene-5‚ 6-endo-dicarboxylic anhydride Introduction: The Diels-Alder reaction is a [4+2] cycloaddition of a conjugated diene and a dienophile. This type of reaction was named for Otto Diels and Kurt Alder who were the first to investigate this reaction (Weldegirma‚ 2012). The Diels- Alder reaction is one of the most important reactions in all of organic chemistry because of the applicability of it. This reaction can form
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Introduction: The Diels-Alder reaction is one of the most powerful tools used in the preparation of important organic molecules. When two carbon-carbon double bonds are positioned next to one another‚ a conjugated diene is formed. Conjugated dienes undergo a cycloaddition reaction (also called pericyclic addition) with certain double bonds to afford cyclohexenes and related compounds. The reaction of Cyclopentadiene with Maleic anhydride is an example of a Diels-Alder reaction. This reaction forms a six-membered
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Cyclic dienes added to alkene dienophiles also lead to two new form of stereoisomeric products‚ the endo and exo products (Kilway‚ “Lecture”). In cases where dienes and dienophiles align above one another‚ the endo product is formed (Hunt). The endo product will have two axial substituent groups (Kilway‚ “Lecture”). This formation typically forms the major product because it takes less kinetic energy to be formed due to secondary orbital interactions with the substituents in transition states (Hunt)
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2013 “Reaction Classes and Pericyclic Reactions” ● 4 Lectures ● Recommended Texts: (i) J. March “Advanced Organic Chemistry”‚ p 839‚ `---Edn.‚ Oxford (W); Warren (2) Ch 34‚ 35. Syllabus 1) General principles (a) Reaction classes (i) Heterolytic (ii) Homolytic (iii) Pericyclic (b) Pericyclic Reaction Types 2) Electrocyclic Reactions (a) Definition and examples (b) Stereochemical aspects and the Woodward and Hoffmann rules 3) Cycloaddition Reactions (a) Definition
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Conjugated linoleic acid‚ is a form of linoleic acid‚ an omega-6 fatty acid important to human health (Wang and Jones‚ 2004). The CLA is formed by the bacteria in rumen of certain ruminants but not for humans. It is obtained by humans from dietary sources such as beef‚ lamb and dairy products including milk and cheese (Wang and Jones‚ 2004). CLA is an antioxidant‚ anti-carcinogenic‚ anti-diabetogenic‚ anti-atherosclerotic‚ anti-catabolite as well as an immune system enhancer (Belury‚ 2002). Health
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majority of your time is spent in the past or future‚ but rarely living in the realism of NOW.’ - Shannon L. Alder The quote listed above by Shannon Alder is very meaningful and thought provoking‚ relating to not just people who suffer from personality disorders‚ but to anyone that may occasionally be conflicted with stress‚ anxiety‚ or any other forms of suffering. Prioritizing the focal point‚ Alder acknowledges how the ‘true definition’ of a mental illness is over-contemplating our past or future when
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On what I have seen‚ the first experiment showed chemical reaction to be more specific‚ combustion. In the experiment the Potassium permanganate (KmnO4) was used as the oxidant‚ and obviously oil as the fuel. As the two were mixed they needed to release energy in form of heat‚ that’s where combustion occurs. I learn that Combustion is the sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat and conversion of chemical species. The release of
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Alfred Alder Feb. 7th‚1870 - May 28th‚ 1937 Alfred Alder is a psychologist whom was born in Vienna‚ Austria. As a child‚ Alfred suffered with Rickets. Rickets is a disease that is caused by a lack of vitamin D‚ calcium‚ or phosphate. Rickets leads to the softening and weakening of the bones. Because of Alder having this disease‚ he was restricted to a wheel chair until the age of four when he was able to walk on his own. Due to Alder having
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STEM AND LEAF CHARACTERIZATION OF Eucalyptus deglupta Austria‚ C.‚ Batenga‚ B.‚ Daysa‚ R.‚ Dela Rosa‚ J.‚ Rebong‚ C.1 1 Department of Biology‚ College of Science‚ University of Philippines Baguio Baguio City‚Philippines INTRODUCTION bole that reaches up to 240cm (Figure 1a). It has a multi colored bark that varies from green‚ yellow‚ bluish‚ purplish‚ pink and orange. It has a green under bark and right before exfoliation occurs‚ the bark changes to brownish maroon (Figure 1b). The colors
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The Stock Market Reaction to Oil Price Changes Sridhar Gogineni Division of Finance Michael F. Price College of Business University of Oklahoma Norman‚ OK 73019-0450 March 13‚ 2008 Abstract I explore the reaction of the stock market as a whole and of different industries to daily oil price changes. I find that the direction and magnitude of the market‟s reaction to oil price changes depend on the magnitude of the price changes. Oil price changes most likely caused by supply shocks have a
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