(assign stereochemistry of dibromo product‚ why selective?‚ is this molecule chiral?) Bromine was added to Estilbene to form an anti product. This happened because no true carbocation was formed in reaction. Instead‚ there was an intermediate where one of the bromine atoms was partially bonded to both carbon atoms of the double bond. This prevented bond rotation around the carbon-carbon bond. The steric hindrance prevented the bromine from being added to the same side as the first bromine atom. Thus
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LAB REPORT! EXPERIMENT#5‚6! MANPREET KAUR KHAIRA! LAB PARTNER: VIAN RAIES! The purpose of this lab exercise was to perform the bromination of (E)-1‚2-diphenylethene (trans-stilbene) by addition reaction in which bromine was added across the double bond to yield a vicinal dibromide. The next step was to perform a double elimination reaction by product gained to synthesize an alkyne‚ that is‚ 1‚2-diphenylacetylene. The two major techniques used in this lab were TLC analysis and UV-vis spectroscopy
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1. Which of the following are the products of a homolytic cleavage of a C-C bond of ethane? A) 2 B) CH3 CH3 C) H D) 2 + + CH3 CH2H3 CH3 Ans: A Chapter 11 Topic: Radicals Section: 11.1 Difficulty Level: Easy 2. Which of the following is the most stable radical? A) B) C) D) E) Ans: B Chapter 11 Topic: Radicals Section: 11.1 Difficulty Level: Easy 3. In the molecule shown below‚ determine which of the labeled bonds is
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with zinc and acetic acid‚ C yields only: O O The structure of C is: I II IV A) B) C) D) E) III V I II III IV V Ans: E Topic: Structure Elucidation 4. Compound X has the molecular formula C6H10. X decolorizes bromine in carbon tetrachloride. X also shows IR absorption at about 3300 cm-1. When treated with excess hydrogen and a nickel catalyst‚ X yields 2-methylpentane. The most likely structure for X is: A) B) C) D) E) Ans: D 243 Keghan Chapter
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Bromobenzene undergoes no reaction for both SN1 and SN2. This is because bromobenzene is very stable‚ and contains allylic and vinyllic bromine‚ which is also very stable‚ and cannot be a good nucleophile. Bromocyclopentane reacts under SN1 and SN2‚ but it shows a faster reaction in AgNO3/ethanol reagent‚ that is SN1. This is because bromocyclopentane is secondary bromine‚ and have bigger steric strain‚ since it is a cyclic compound. The bigger steric in a molecule‚ the harder it is for the nucleophile
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Synthesis of 4‐methylcyclohexene via Dehydration of 4‐methylcyclohexanol Heston Allred TA: Christine Woolley Thursday 1:05-4 pm Laboratory Experiment #10 Abstract 4-methylcyclohexanol was synthesized to 4-methylcyclohexene using dehydration. 4-methylcyclohexanol was heated to reflux and the subsequent distillate (4-methylcyclohexe) was collected. It was then purified using sodium chloride to separate products and an anhydrous solid was then added and filtered
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Z- based on the Cahn-Ingold-Prelog priority rules (review) Stability: There are 3 factors that influence alkene stability: 1. Degree of substitution: more highly alkylated alkenes are more stable‚ so tetra > tri > di > mono-substituted. 2. Stereochemistry: trans > cis due to reduced steric interactions when R groups are on opposite sides of the double bond. 3. Conjugated alkenes are more stable than isolated alkenes. |[pic] |[pic] |more stable than |[pic] |[pic] | |trans-2-butene
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6753_Klein_00.qxd 5/1/07 5:02 PM Page ii 6753_Klein_00.qxd 5/1/07 5:02 PM Page i 6753_Klein_00.qxd 5/1/07 5:02 PM Page ii 6753_Klein_00.qxd 5/15/07 2:14 PM Page iii ORGANIC CHEMISTRY I AS A SECOND LANGUAGE Second Edition DR. DAVID R. KLEIN Johns Hopkins University JOHN WILEY & SONS‚ INC. 6753_Klein_00.qxd 5/1/07 Marketing Manager Production Manager Production Editor Cover Designer 5:02 PM Page iv Amanda Wygal Pamela
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products and why? What are the three types of carbocation rearrangements and why do they occur? Stereochemistry of Reactions (read 6.14 in 7th edition before class) What are the three ways a reaction can have stereochemistry? (a) What is regioselective? (b) What is stereoselective? (c) What is stereospecific? What type of stereochemistry is there in the following three scenarios? (a) Addition reactions that form one asymmetric center. What is the product if the reactant has no asymmetric
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Alkyl Halides Alkyl halides are a class of compounds where a halogen atom or atoms are bound to an sp3 orbital of an alkyl group. CHCl3 (Chloroform: organic solvent) CF2Cl2 (Freon-12: refrigerant CFC) CF3CHClBr (Halothane: anesthetic) Halogen atoms are more electronegative than carbon atoms‚ and so the C-Hal bond is polarized. H H μ C + C-l δ δ H The C-X bond is polarized in such a way that there is partial positive charge on the carbon and partial negative charge on the halogen. Dipole moment
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