Name__________________________ Chemistry 190: Organic Chemistry EXAM 3 Thursday April 21‚ 2011 1. (12) ______ 2. (14) ______ 3. (20) ______ 4. (12) ______ 5. (54) ______ 6. (16) ______ 7. (12) ______ 8. (10) ______ Total (150) ______ The exam consists of twelve numbered pages and an unnumbered cover sheet. Make certain that you have a complete exam. You will have two hours to work on the exam. No books or notes are allowed; however‚ you may use a molecular model set and a calculator
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Amanda Jornd Experiment 7- Synthesis and Reactivity of tert-Butyl Chloride Via an SN1 Reaction Introduction/Background: Alkyl halides are compounds in which a halogen atom replaces a hydrogen atom of an alkane. Alkyl halides are classified as primary‚ secondary or tertiary depending on the number of alkyl substituents directly attached to the carbon attached to the halogen atom. The purpose of this lab was to properly prepare t-butyl chloride from t-butyl-alcohol in a concentrated hydrochloric
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(Exp 24‚ pp 211-221‚ pp 808-823‚ pp 836-842) Purpose: The purpose of this experiment is to determine the nucleophilic strength of chloride and bromide ions as it reacts with 1-butanol (n-butyl) and 2-methyl-2-propanol (t-butyl alcohol) under SN1 and SN2 conditions. Method: 40 g of ice and approximately 30 ml of sulfuric acid is cautiously added to a 100 mL beaker respectively. Weigh 7.6 g of ammonium chloride and 14.0 g of ammonium bromide and place it in another beaker‚ crushing the lumps
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Objectives After studying this Unit‚ you will be able to • name haloalkanes and haloarenes according to the IUPAC system of nomenclature from their given structures; • describe the reactions involved in the preparation of haloalkanes and haloarenes and understand various reactions that they undergo; • correlate the structures of haloalkanes and haloarenes with various types of reactions; • use stereochemistry as a tool for understanding the reaction mechanism; • appreciate the applications of organo-metallic
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Experiment 21: Reaction of some Akyl Halides Completed on November 13‚ 2012 Purpose The purpose of this experiment was to examine reactiveness of 10 organic compounds under both SN1 and SN2 conditions. Table of Chemicals Compound Structure Molecular Weight (g/ml) Boiling Point (°C) Melting Point (°C) Density (g/ml) Safety 1-bromobutane 137.03 102 -112 1.269 Flammable‚ irritant 2-chloro-2-methylpropane 92.57 51 -26 0.89 Flammable‚ irritant acetone 58.08 56.5 -95 0.793 flammable
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September 2‚ 2013 Course/Yr. : BS Chemistry III Sched : MF 7-10‚ Group#2 Experiment No. 1 Synthesis and Reactivity of Tert-Butyl Chloride I. Objectives : 1. To produce tert-butyl chloride from tert-butyl alcohol 2. To understand the SN1 and SN2 mechanism involved in the reaction 3. To determine the yield of percentage of t-butyl chloride II. Introduction An alkyl halide is a derivative of alkanes. Alkanes are hydrocarbons with a functional group C-C. The hydrogen atom is then replaced
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Cyclohexylmethanol and 1-methylcyclohexanol are converted to their corresponding bromides. Write a suitable mechanism for each reaction‚ and assign each the appropriate symbol (SN1 or SN2). OH O H H Br H + :Br : SN2 :Br : O H H Br + H2O OH O H Br O + H2O + :Br : SN1 :Br : Br 7. Give the structure of the principal organic product formed by photochemical bromination of methylcyclopropane‚ draw the mechanism of the reaction. Br2‚ h
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Haloalkanes Haloalkanes are organic compounds in which one or more halogen atoms are covalently bonded to saturated carbon. General formula is CnH2n+1X. X is a halogen atom (F‚Cl‚Br‚ or I) Classification of haloalkanes We classify a C atom as 1º‚ 2 º or 3 º according to the number of the C atoms attached to it. Nomenclature of haloalkanes Haloalkanes are named by adding prefix fluoro‚ chloro‚ bromo or iodo to the name of the corresponding alkanes. Physical properties of haloalkanes
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|Chapter 5: | |Structure and Preparation of Alkenes. | |Elimination Reactions | Summary Alkenes contain the C=C functional group which can be prepared by 1‚2-elimination reactions such as: • dehydration of alcohols (- H2O) or • dehydrohalogenation of alkyl halides (- HX). Zaitsev’s rule indicates that the preferred product is the more highly substituted
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bromine.) Alkyl halides are very important since they are used in many of the products used today. They can be synthesized by means of adding alcohols to hydrogen halides (such as HCl‚ HI‚ or HBr) resulting in nucleophilic substitution (specifically the SN1 reaction.) The experiment was done with the goal of synthesizing an alkyl halide from alcohol and a hydrogen halide. In order to do this‚ tert-butyl alcohol was mixed with HCl to form crude tert-butyl chloride. Solid NaHCO3 and CaCl2 were used to prevent
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