Our product was trans-p-anisalacetophenone and it was produced from the ketone reacting with the aldehyde. The ketone does not react with itself because the aldehyde is sterically favored and the carbon on it is more likely to be attacked by the nucleophile than the carbon on the ketone. If the ketone were to attack itself‚ much more
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guess paper 1. Express the rate of following reaction in terms of disappearance of hydrogen in the reaction. 3H2(g) + N2(g) 2NH3(g) 2. What is peptisation? 3. Write Reimer Tiemann reaction. 4. Why is CO stronger ligand that Cl-. 5. Write structure of 2-(2-Bromophenyl)butane. 6. Complete the reaction C6H6+R COCl 7. Why pentahalides more covalent than trihalides? 8. What is difference between nucleoside and nucleotide? 9. Explain the following- (a) Gattermann Koch
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In the reaction mechanism‚ a carboxylic acid‚ m-toluic acid is used to synthesize N‚N-diethyl-m-toluamide‚ also know as DEET‚ through a nucleophilic acyl substitution reaction. The reaction begins by first converting the m-toluic carboxylic acid into an acyl chlorosulfite through a reaction using thionyl chloride. The carboxylic acid is converted into an acyl chloride because the acyl chloride is more reactive. In this step‚ hydrochloric acid is formed from a hydrogen on the carboxylic acid and a
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Exp 23 B Synthesis of t-Pentyl Chloride 11-8-12 Purpose: The sysnthesis of t-Pentyl Chloride from alcohol. Procedure: Preparation of t-Pentyl Chloride. In a 125-mL separatory funnel‚ place 10.0 mL of t-pentyl alcohol (2-methyl-2-butanol‚ MW _ 88.2‚ d _ 0.805 g/mL) and 25 mL of concentrated hydrochloric acid (d _ 1.18 g/mL). Do not stopper the funnel. Gently swirl the mixture in the separatory funnel for about 1 minute. After this period of swirling‚ stopper the separatory funnel and
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The purpose of this experiment was to perform a wittig reaction‚ the horner-emmons wittig specifically‚ reacting an aldehyde with an ylide to make an alkene. This particular variation of the wittig reaction has several advantages: It gives only the trans product; it uses a much milder base that is easier to handle; and it gives a water soluble byproduct which is easy to separate from the product. The reason that these advantages occur is a change in the structure of the ylide. Instead of a tripheylphosphine
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The purpose of this experiment was to synthesize triphenylmethanol from a Grignard reagent. The Grignard reaction technique was used in this synthesis but due to the fact that it is such a strong nucleophile and base‚ it was important to prevent water from interfering with the Grignard reaction. Purity of the product was determined by measuring the melting point. Reagent Table: Structure Name Molecular formula Molar mass Density Melting point Boiling Point Diethyl ether C4H10O
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Discuss a range of analytical techniques used for the purification of proteins What are proteins? Proteins are the main building blocks of life. They are essential for the body and have many different roles . Proteins are made from sequence of amino acids. Protein structure is determined by their sequence of amino acids‚ which are linked by peptide link. Proteins are made from about 50 to 2000 amino acid residues. Figure 1 Why purify proteins? They are many reasons why a biochemist
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temperature‚ solvent polarity‚ and structure. It is particularly observed in tertiarhalides i.e. in SN1mechanism‚ Nucleophilic Substitution which is in 1storder. It is basically a reaction that involves substitution by a solvent that pretendslikea nucleophile i.e. it donates electrons. The reaction being in firstorder means the rate of the reaction depends on the concentration of only one reactant. Table of Reagents used: Name | Molar Mass (g/mol-1) | Density (g/cm3) | Boiling Pt ( C) | Melting
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C H EM 301A - O rganic Chem istry L ecture N otes © Dr. Peter de Lijser‚ 2011 Introduction – Welcome to O-chem! “What is Organic Chemistry?” Organic chemistry is the chemistry of Carbon. “Why is Organic Chemistry Important for me?” Organic Chemistry is the central science for many other fields: • Medicine/Pharmacy: • Biochemistry: • Industrial Applications: • Reaction Mechanisms: What do "Organic Chemists" do? • Discover new reactions • Improve old reactions
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Vidallon‚ Mark Louis P. Date Performed: February 20‚ 2012 CHEM44.1 2L Date Submitted: March 12‚ 2012 MIXED-ALDOL CONDENSATION Synthesis of Cinnamaldehyde I. Introduction Cinnamaldehyde‚ cinnamic aldehyde or 3-phenyl-2-propenal is the major constituent of cinnamon oil‚ extracted from several species of Cinnamomum (C. verum‚ C. burmanii‚ C. cassia)‚ under the family Lauraceae‚ a group of evergreen trees. Cinnamon bark (particularly C. verum) yields 0.4-0.8% oil‚ which contains 60-80% cinnamaldehyde
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