Compound 50‚ like its known analogue 3‚ involves an α‚β-unsaturated ketone‚ an acid-sensitive reactant‚ which prevents its direct synthesis in presence of protic solvents by refluxing. Despite of this characteristic‚ 50 was formed smoothly in 5 minutes by grinding chemistry‚ solely as E-isomer‚ without any evidence of decomposition after 1H and 13C MNR analysis. This synthetic approach provides easy access to such α‚β-unsaturated N-acylhydrazones‚ which are building blocks in the synthesis of nitrogen-containing
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“50 First Dates” In the movie‚ Lucy Whitmore‚ an art teacher living in Hawaii‚ is involved in a horrible car accident which causes severe brain damage to her temporal lobe‚ or more specifically‚ the area containing her hippocampus. This area of the brain is crucial in forming new memories. The brain damage causes Lucy to suffer from short-term memory loss. On the subject of psychology‚ this movie has accurately demonstrated characteristics of someone who has suffered damage to the hippocampus region
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WHEN PIGS FLY!!! Throughout the Canterbury Tales by Geoffrey Chaucer‚ participants of the pilgrimage tell stories to entertain one another. These stories‚ while amusing‚ tend to have an underlying message‚ one being the Franklin’s Tale. The Franklin’s Tale is the most moral tale that has been read. It is not told to make the other pilgrims laugh‚ rather to explain an extremely important lesson. Throughout life‚ people say many things that are meant to be taken with a grain of
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to as the Dream by Coates‚ has existed throughout the history of the United States. The Dream existed in the 19th century as the Manifest Destiny‚ the belief that the expansion of the United States into the American continent was destined to occur. Ta-Nehisi Coates brings a new perspective onto this ideology‚ the idea that this Dream was created and achieved at the expense of the lives of others. The people living in the Dream are the citizens of the United States‚ who believe that they have the
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Sonnets 50 and 51 paired together depict a theme of travel. Specifically‚ the speakers travels on horseback. These travels cause him great despair because he is leaving behind his beloved young man. Shakespeare begins the poem with “How heavy do I journey on the way”. Heavy is describing the emotional burden he feels as he reluctanly leaves his friend. As the sonnet continues‚ the speakers feelings of misery become greater. Consequently‚ he draws an analogy between himself and the horse
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a while. However E.L James British author adds her own erotic twist to her novel 50 Shades of Grey. The books use of unusual sexual acts has quickly sparked controversy and has people talking globally. With her series selling over 70 million copies (Street‚ 2013) and surpassing Harry Potter as the fastest selling paperback off all time (Bentley‚ 2012). Fifty Shades of Grey has easily impacted popular culture. 50 Shades of Grey set up the series as the two main characters Anastasia Steele and Christian
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1960’s originated in the 50’s‚ including new attitudes toward sex and the family and a new interest in ethnicity and diversity. Jewish and black writers‚ even a few openly gay writers‚ cut a path for the multicultural writers of the 80’s and 90’s. The margins of the culture were beginning to erode the conservative center. Elvis was influenced by black rhythm and blues‚ while writers like Norman Mailer and Jack Kerouac idealized black culture. Counterculture writers of the 50’s were fascinated by jazz
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1788. Massachusetts Originally part of the thirteen colonies‚ Massachusetts became a state on February 6‚ 1788 Maryland Maryland became the seventh state on April 28‚ 1788. During the Civil War‚ President Abraham Lincoln placed Maryland under military control. South Carolina South Carolina‚ one of the thirteen colonies‚ became the eighth state on May 23‚ 1788. On December 20‚ 1860‚ South Carolina became the first state to secede form the Union. It re- entered after the Civil War. New Hampshire
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restricted by business‚ the media‚ and by social pressures” –Brett Harvey. What the world didn’t understand was how hard it was for women to lose their independence all over again‚ unfortenoutly it back fired on America. Over time by the end of the late 50’s there was a rising birth rate‚ a stable divorce rate‚ and declining age of marriage. Today 4.95 per 1‚000 people divorce here in America (University Libraries‚ Ohio University )‚ there are more single parent homes prodominantly by the mother‚ there
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General The 50’s was the decade that gave us the still well known and well loved music genre of Rock’n’Roll. Other than Rock’n’Roll country music‚ traditional pop‚ and rhythm and blues were the main genres of the 50’s. Rock’n’Roll Bill Haley & His Comets‚ a group that was founded in 1952‚ were some of the first to play this specific genre In 1954 the Bill Haley’s “Rock Around the Clock” became the first song ever used for a movie’s soundtrack. Is believed to be a mix of rhythm‚ blues‚ and country
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