alpha hydrogen is acidic because of its location near the carbonyl on acetophenone. When the sodium hydroxide is added‚ it deprotonates the hydrogen and creates an enolate ion. This deprotonation creates a nucleophilic carbon that can attack an electrophilic carbon (like a parent carbon of a carbonyl). This enolate ion is a resonance structure and the oxygen atom and the corresponding pi bond it can form can stabilize the negative charge. When the nucleophilic pi bond attacks the carbonyl carbon (the
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Electrophilic addition causes N2 to be lost‚ which is a thermodynamically favourable process‚ resulting in the formation of a stable carbene. The carbene is the intermediate and in this reaction‚ it is a highly reactive‚ neutral molecule. The carbene acts as
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alkenes. Alkanes only contain c-c single bonds‚ are saturated‚ and are the least reactive. Alkenes are c=c double bonds‚ more reactive than alkanes‚ and unsaturated. In the next part of the experiment we added bromine to alkenes. This caused an electrophilic halogenation reaction. If the bromine reacted with the alkene the bromine would discolor from orange and turn clear. Experiment Part A) Solubility of Alkanes: 1 mL of nine solvents (water‚ methanol‚ n-butanol‚ ethylene‚ glycol‚ acetone‚ hexane
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derivatives of carboxylic acids. 5. Describe both the diene and dieneophile in Diels-Alder reactions. 6. Describe the process of ultraviolet light absorption by organic molecules. 7. Identify the order of reactivity of aromatic compounds in Electrophilic aromatic substitution. 8. Classify alcohols and amines as primary‚ secondary or tertiary. 9. Interpret infrared and 1H NMR spectra for: a. Aldehydes b. Ketones c. Carboxylic acid d. Derivatives of carboxylic acid. 10. Identify each of the
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Lab 1: Synthesis of Aspirin Introduction: The purpose of this lab was to demonstrate the ability to easily alter the molecular structure of a compound to greatly increase its utility. In this case‚ an acetyl group was added to salicylic acid‚ a naturally occurring compound with significant pharmaceutical value. Without the addition of the acetyl group‚ salicylic acid is an irritant to the gastro-intestinal (GI) tract. Once the acetyl group is added via a simple reaction‚ acetylsalicylic
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Quiz #1 Attempt 1 Written: Jul 7‚ 2012 9:48 AM - Jul 7‚ 2012 9:50 AM Submission View Your quiz has been submitted successfully. Question 1 1 / 1 point At what time do you have to complete your online prelab assignment to be allowed to participate in the lab? Question options: A week before the lab Day before the lab at 10 pm The morning of lab day at 8 am One hour before the lab Question 2 1 / 1 point Which materials/chemicals belong in the desiccator? Question options: Drying
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REACTIONS OF HYDROCARBONS Diane Cate Satsatin Biology Student‚ Biology Department College of Science‚ De La Salle University-Dasmarinas ABSTRACT Five substances which are Hexane‚ Eugenol‚ Unknown hydrocarbon 1‚ Unknown hydrocarbon 2‚ and Acetylene gas was used for the selective reactivity of hydrocarbons to functional group tests; Bayer’s test‚ Bromine test light‚ Bromine test dark‚ and Tollen’s test. In Bayer’s test‚ only Acetylene‚ Eugenol and Unknown hydrocarbon 2 reacted positively
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Bromination Solo Experiment 3 – Individual Lab Report (Save as pdf and submit‚ due by 12:00 NOON one week after experiment) Last Name: First Name: TA Name: Date Lab Performed: Date Lab Submitted: Group A‚ B‚ or C: Comments for Grading TA: (Please indicate if you performed the lab on a day other than your regularly scheduled day and/or with a TA other than your regular TA). Page Limit: report must not exceed FIVE pages (including this page) LIMIT DOES NOT INCLUDE ANY GRAPHS‚ SPECTRA
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UNITED ARAB EMIRATES UNIVERSITY FACULTY OF SCIENCE DEPARTMENT OF CHEMISTRY GUIDELINES FOR ORGANIC CHEMISTRY NON-MAJORS CHEM 181 By Dr. Haythem Ali Saadeh Fall‚ 2012 Course Title: ORGANIC CHEMISTRY for Non-Majors Course Number: CHEM 181 Prerequisite: General Chemistry Credit Hours: 2 Cr. Hrs. (comprises of 2 hrs. lecture per week) Course Instructor: Dr. Haythem Ali Saadeh h.saadeh@uaeu.ac.ae Textbook: “Organic Chemistry: A Short Course” By
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13. ORGANIC CHEMISTRY IV) ALKYNES SYNOPSIS Alkynes are commonly known as acetylenes. Acetylene is the simplest and important member of the alkyne series. • Alkynes contain – C ≡ C – • General molecular formula of alkynes is CnH2n–2 • Triple bonded carbons are ‘sp’ hybridized and greater s – character is associated with it. • Alkynes will exhibit chain‚ position and functional isomerism. • Their functional isomers are alkadienes and cyclo alkenes. • The minimum number of carbons required to exhibit
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