1. Summary of Experiment In this experiment we will be comparing the both SN1 and SN2 reactions using various compounds and sodium iodide and silver nitrate. We will be comparing the nature of the leaving group (Cl vs Br) in the 1-halobutanes as well as the effect of the structure of the compound. The effect of the solvent polarity and temperature will also be looked at. Name Structure M.W. M.P. B.P. Density
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FLORIDA INTERNATIONAL UNIVERSITY Department of Chemistry CHM 2211-U02– ORGANIC CHEMISTRY II PRACTICE EXAM I CHM 2211-U01 SAMPLE EXAM I‚ Page 2 Type of Vibration C-H Frequency (cm-1) 3000-2850 1450 and 1375 1465 3100-3000 1700-1000 3150-3050 1000-700 ca. 3300 2900-2800 2800-2700 1680-1600 1600-1400 2250-2100 1740-1720 1725-1705 1725-1700 1750-1730 1700-1640 1810 and 1760 1300-1000 Intensity s m m m s s s m w w m-w m-w m-w s s s s s s s Alkanes -CH3 -CH2Alkenes (stretch) (bend) (bend)
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UNIVERSITY FACULTY OF SCIENCE DEPARTMENT OF CHEMISTRY GUIDELINES FOR ORGANIC CHEMISTRY NON-MAJORS CHEM 181 By Dr. Haythem Ali Saadeh Fall‚ 2012 Course Title: ORGANIC CHEMISTRY for Non-Majors Course Number: CHEM 181 Prerequisite: General Chemistry Credit Hours: 2 Cr. Hrs. (comprises of 2 hrs. lecture per week) Course Instructor: Dr. Haythem Ali Saadeh h.saadeh@uaeu.ac.ae Textbook: “Organic Chemistry: A Short Course” By Harold Hart‚ Leslie E. Craine
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Relative Reactivity of Anilines Abstract: Various Anilines were tested with Br2/HBr solution‚ the products were crystallized and melting points attained to verify relative reactivity. My assignment‚ 2‚4-Dibromoanisol‚ was prepared in a yield of 52% with a melting point of 55-58 C . Reaction: Mechanism: Procedure: Anisole (0.35mL‚ 0.0378mol) was obtained and placed in a pre-weighed 25 mL round bottom flask‚ along with 2.5 mL of glacial acetic acid and a magnetic stir bar. Then the
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of the given names. 1. Draw: cis-4-tert-butylcyclohexanol ANS: 2. Draw: 3-methyl-2-buten-1-ol ANS: 3. Draw: 2-phenyl-2-propanol ANS: 4. Draw: glycerol ANS: 5. Draw: 2‚ 4‚ 6-trinitrophenol ANS: IUPAC Naming Instructions: Provide proper IUPAC names. 6. Name: ANS: (E)-2-ethylbut-2-en-1-ol 7. Name: HOCH2CH2OH ANS: 1‚ 2-ethanediol or ethylene glycol 8. Name: ANS: allyl alcohol or 2-propen-1-ol 9. Name:
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forming CH3COO- and H3O+. As a result of the reaction‚ the equilibrium amounts of CH3COOH and H2O will be less; for every mole of CH3COO- formed‚ one mole of CH3COOH and one mole of H2O will react. The equilibrium constant expression Kc for Reaction 1 is: Kc = [CH3COOH] / [H3O+][CH3COO-] The value of Kc is relatively constant at a given temperature. This means that mixtures containing CH3COOH and H2O will come to equilibrium with the same value of Kc‚ no matter what initial amounts of CH3COOH and
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Chemistry SL Internal Assessment: Enthalpy Change Design Lab Experiment: Reaction of distilled water and solid sodium hydroxide RESEARCH QUESTION How does the heat released during the reaction between distilled water and Group 1 elements (lithium‚ sodium and potassium) vary as one goes down the group? OBJECTIVE The objective of the experiment is to measure the heat change during the reactions with minimal heat loss to the surroundings. MATERIALS The materials to be used in this experiment
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Preparation and SN1 Reactivity of 2-Bromobutane Whitney Bellido Department of Chemistry‚ Illinois State University‚ Normal‚ IL 61790-4160 Submitted: April 4th‚ 2013 Introduction The overall goal of this experiment is to understand and be familiar of SN1 reactivity. We also learned how to prepare 2-Bromobutane by learning how to distill and extract this product from its organic layer. Finally‚ another goal was to specifically understand the relative reactivity of alkyl halides under SN1 conditions
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Directorate of Education‚ Delhi SOME IMPORTANT REASONING BASED QUESTIONS OF ORGANIC CHEMISTRY 1. Chlorobenzene is less reactive than chloromethane. Ans. In chlorobenzene‚ each carbon atom of benzenering is sp2 hyridised and is electron withdrawing. Chlorine atom donates a lone pair of electron and acquire positive charge. The negative charge is delocalised on ortho and para position by resonance. C-Cl bond acquires partial double bond character and is 169 pm as compared to 17.0 pm in chloromethane where
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Sample Questions 1. In the chemical formula for ammonia‚ NH3‚ what does the subscript 3 represent? (a) the number of ammonia molecules that will bond together (b) the number of nitrogen atoms in each molecule of ammonia (c) the number of nitrogen and hydrogen atoms in each molecule of ammonia (d) The number of hydrogen atoms in each molecule of ammonia 2. The diagram above shows a block from the periodic table. The number six represents the following consumers eats only producers? (a) atomic
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