In this experiment the objective was to perform a Diels-Alder reaction using cyclopentadiene and maleic anhydride to synthesize the product‚ cis-Norbornene-5‚6-endo-dicarboxylic anhydride. The Diels-Alder reaction is one of the most important reactions in organic chemistry and was first investigated by Otto Diels and Kurt Alder in Germany. It is a [4+2] concerted cycloaddition reaction which involves a diene and a dienophile. The Diel-Alder reaction are mainly used for creating new carbon-carbon
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THEORY: The Diels-Alder cycloaddition reaction was discovered by Otto Diels and Kurt Alder and is very useful in the synthesis of polycyclic compounds. The Diels-Alder reaction can be described as: [4+2] cycloaddition- a diene with 4 π electrons + 2π electrons from the dienophile; a pericyclic concerted reaction- meaning the reaction occurs in a single step (no intermediates) and involves a cyclic redistribution of bonding electrons. In order for a Diels-Alder reaction to take place
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Organic Chemistry II Lab Diels Alder Reaction Purpose: In this experiment a Diels-Alder reaction was used to form the products. Cyclopentadiene and maleic anhydride were reacted together to form cis-Norbornene-5‚6-endo-dicarboxylic anhydride. 7-oxabicyclo{2.2.1}hept-5-ene-2‚3-dicarboxylic anhydride was also produced through a Diels-Alder reaction with the combination of furan and maleic anhydride. Equation: Procedure: Part 1 In a flask equipped with
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Lab #4 May 26‚ 2015 Diels Alder Reaction Introduction: Diels Alder Reaction is the reaction of a diene with a species capable of reacting with the diene‚ the dienophile. A diene is a hydrocarbon that contains two carbon double bonds‚ while a dienophile is an electron-deficient alkene. The Diels-Alder is also called a [4+2] cycloaddition because a ring is formed by the interaction of four pi electrons of the alkene with two pi electrons of the alkene or alkyne. The product of the Diels-Alder
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The Diels-Alder Reaction Submitted by: Joe Student Partner: Jill Student Date: February 8‚ 2005 TA: Super TA Reaction +OOOxylene140 oCOOO Data Table Reagents MW Grams used Lit. Mp Anthracene 178.23 g/mol 1.023 g 216-218ºC Maleic anhydride 98.06 g/mol 0.497 g 54-56ºC Products MW Grams obtained Lit. Mp Observed Mp Crude product 276.29 g/mol 1.362 g 261-262ºC 260.2-261.3ºC Recryst. Product 276.29 g/mol 1.283 g 261-262ºC 261.3-261.9ºC Results and Discussion Discuss the
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Diels-Alder Reaction Heather Jost Lab Partner: Jasmina Salcinovic CHEM2642L Luise Strange de Soria Georgia Perimeter College September 29‚ 2004 Diels-Alder Reaction Resources: Mayo‚ Pike‚ Trumper‚ Strange de Soria. Microscale Organic Laboratory. New York: John Wiley and Sons‚ 2002. Strange de Soria‚ Luise. “Student Survival Guide”. http://www.gpc.edu/~lstrange/2642lab/survivalguide/grignard2.pdf. 2004. Purpose: The purpose of these experiments
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Introduction The Diels-Alder Reaction is a reaction used in organic chemistry that builds rings very efficiently (1)‚ this cycloaddition process allows for the stereoselective formation of cyclohexene rings possessing as many as four contiguous stereogenic centers (3). This reaction occurs without intermediates‚ in a single step‚ which explains the stereospecificity due to substituents not being given the chance to “switch around”. (1)These six membered rings are synthesized by reacting a dienophile
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Brittany Martin 2/13/2014 Diels Alder reaction of anthracene and Maleic anhydride Reaction Scheme: Figure one shows the reaction scheme for Diels Alder reaction of anthracene and maleic anhydride Theory/Background: The Diels-Alder reaction was created in 1928 by two German chemists Otto Diels and Kurt Alder (Wade‚ Jr.‚ 2013). This reaction is best used for making six membered rings with different functional groups. The reaction is called a 4+2 cycloaddition because a ring is formed
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Lab 2B: Diels-Alder Reaction Zhouxiang Xu TA: Bhumasamudram Jagadish Experiment performed: Jan 28th‚ 2014 Report Due: Feb 10th 2014 Result: For the Diels-Alder reaction: Maleic acid is 0.002 mol 2‚3-dimethyl-1‚3-butadiene is 0.002 mol The theoretical yield is 0.36g Cycloaddition product is 0.358g (maybe it was not completely dry when I weighted.) The % yield of Diels-Alder reaction is 99.4% For the hydrolysis: The theoretical yield of hydrolysis is 0.396g The
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EXPERIMENT OBJECTIVE The aim of this experiment is synthesize hexaphenylbenzene via an aldol condensation reaction‚ followed by a Diels-Alder [4+2] cycloaddtion. This is final step in the multistep synthesis pathway to form hexaphenylbenzene‚ and uses the products of the previous experiments: benzil and diphenylacetylene REACTION DIAGRAM TABLE OF REAGENTS BENZIL DIBENZYL KETONE TRITON B 40wt% IN METHANOL (1.79 M) TRIETHYLENE GLYCOL TETRAPHENYL-CYCLOPENTA-DIENONE DIPHENYL ACETYLENE
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