gravimetric analysis of Ca as CaC2O4
Gravimetric Analysis of CA2+ as CaC2O4.H2O
Introduction
Weight determination represents one of the most accurate and precise form of measurement carried out in lab analysis. Thus, gravimetric analysis provides a great assay of a variety of analytes. Mixtures of compounds in difference phases provide us with one of the simplest methods of separation and mass explorations. Separating a solid mass from a liquid involves the commonplace technique of filtration. Accordingly, the conversion of an analyte dissolved in a solution to a solid is often the first step in analyzing it. Calcium ions can be analyzed by precipitation with oxalate in a basic solution to form CAC2O4.H 2O.
Ca2+(aq) + C2O42- (aq) + H2O(l) CAC2O4.H 2O(s)
This will yield us large, easy to filter, mostly pure crystals of precipitate if carried out slowly over a long period of time, allowing for proper and complete precipitation. This precipitate is soluble in acidic solution seeing as oxalate anion is a weak base, which allows a slow precipitation by dissolving CA2+ and C2O42- in acidic solution, and gradually raise the pH through the decomposition of urea.
O (heat) C + 3H2O CO2 + 2NH4+ + 2OH- H2N2 NH2 (Urea)
In the end of this process, the mass of the precipitate can be measured very accurately using the funnel with filter paper. Subsequently, because the funnel is ceramic, it can withstand higher temperatures, and thus a more vigorous drying procedure. This allows the maximum amount of water to be removed, and will consequently reduce it as a source of error.
Experimental Method
1. Obtain a Buchner funnel form the drying oven using crucible tongs and place it in a desicooler. Allow the funnel to cool for 60 minutes. Remove from desicooler and add filter paper, and weigh it on an analytic balance. Record the
Introduction
Weight determination represents one of the most accurate and precise form of measurement carried out in lab analysis. Thus, gravimetric analysis provides a great assay of a variety of analytes. Mixtures of compounds in difference phases provide us with one of the simplest methods of separation and mass explorations. Separating a solid mass from a liquid involves the commonplace technique of filtration. Accordingly, the conversion of an analyte dissolved in a solution to a solid is often the first step in analyzing it. Calcium ions can be analyzed by precipitation with oxalate in a basic solution to form CAC2O4.H 2O.
Ca2+(aq) + C2O42- (aq) + H2O(l) CAC2O4.H 2O(s)
This will yield us large, easy to filter, mostly pure crystals of precipitate if carried out slowly over a long period of time, allowing for proper and complete precipitation. This precipitate is soluble in acidic solution seeing as oxalate anion is a weak base, which allows a slow precipitation by dissolving CA2+ and C2O42- in acidic solution, and gradually raise the pH through the decomposition of urea.
O (heat) C + 3H2O CO2 + 2NH4+ + 2OH- H2N2 NH2 (Urea)
In the end of this process, the mass of the precipitate can be measured very accurately using the funnel with filter paper. Subsequently, because the funnel is ceramic, it can withstand higher temperatures, and thus a more vigorous drying procedure. This allows the maximum amount of water to be removed, and will consequently reduce it as a source of error.
Experimental Method
1. Obtain a Buchner funnel form the drying oven using crucible tongs and place it in a desicooler. Allow the funnel to cool for 60 minutes. Remove from desicooler and add filter paper, and weigh it on an analytic balance. Record the
References: 1. K. MacNeil. 2001.The Wine Bible. Workman publishing. . P.93.98 2. Morotta, A. et Al. June 2011. Chemistry 1121 laboratory Manual. Vancouver Community College. p. 33-35 3. M.Cooke,C.Poole. 2010. Encyclopedia of separation science. Oxford press. p. 120-210 4. Petrak Industries. 2013. Drum decanting. Retrieved from: http://www.petrakinc.com/drum-decanting.htm. 5. PBS Velka Bites. 2013. Decanting centrifuges. Retrieved from: http://www.pbsvb.com/decanting-centrifuges