Isotopes and Its Uses

Only available on StudyMode
  • Download(s): 498
  • Published: September 13, 2010
Read full document
Text Preview
ISOTOPES
History of the term:
In the bottom right corner of JJ Thomson's photographic plate are the separate impact marks for the two isotopes of neon: neon-20 and neon-22. The term isotope was coined in 1913 by Margaret Todd, a Scottish physician, during a conversation with Frederick Soddy (to whom she was distantly related by marriage).[4] Soddy, a chemist at Glasgow University, explained that it appeared from his investigations as if each position in the periodic table was occupied by multiple entities. Hence Todd made the suggestion, which Soddy adopted, that a suitable name for such an entity would be the Greek term for "at the same place". Soddy's own studies were of radioactive (unstable) atoms. The first observation of different stable isotopes for an element was by J. J. Thomson in 1913. As part of his exploration into the composition of canal rays, Thomson channeled streams of neon ions through a magnetic and an electric field and measured their deflection by placing a photographic plate in their path. Each stream created a glowing patch on the plate at the point it struck. Thomson observed two separate patches of light on the photographic plate (see image), which suggested two different parabolas of deflection. Thomson eventually concluded that some of the atoms in the neon gas were of higher mass than the rest. F.W. Aston subsequently discovered different stable isotopes for numerous elements using a mass spectrograph. Isotopes are different types of atoms (nuclides) of the same chemical element, each having a different number of neutrons. In a corresponding manner, isotopes differ in mass number (or number of nucleons) but never in atomic number.[1] The number of protons (the atomic number) is the same because that is what characterizes a chemical element. For example, carbon-12, carbon-13 and carbon-14 are three isotopes of the element carbon with mass numbers 12, 13 and 14, respectively. The atomic number of carbon is 6, so the neutron numbers in these isotopes of carbon are therefore 12−6 = 6, 13−6 = 7, and 14–6 = 8, respectively. A nuclide is an atomic nucleus with a specified composition of protons and neutrons. The nuclide concept emphasizes nuclear properties over chemical properties, while the isotope concept emphasizes chemical over nuclear. The neutron number has drastic effects on nuclear properties, but negligible effects on chemical properties. Since isotope is the older term, it is better known, and is still sometimes used in contexts where nuclide might be more appropriate, such as nuclear technology. An isotope and/or nuclide is specified by the name of the particular element (this indicates the atomic number implicitly) followed by a hyphen and the mass number (e.g. helium-3, carbon-12, carbon-13, iodine-131 and uranium-238). When a chemical symbol is used, e.g., "C" for carbon, standard notation is to indicate the number of nucleons with a superscript at the upper left of the chemical symbol and to indicate the atomic number with a subscript at the lower left (e.g. 32He, 42He, 126C, 146C, 23592U, and 23992U). Some isotopes are radioactive and are therefore described as radioisotopes or radionuclides, while others have never been observed to undergo radioactive decay and are described as stable isotopes. For example, 14C is a radioactive form of carbon while 12C and 13C are stable isotopes. There are about 339 naturally occurring nuclides on Earth[2], of which 288 are primordial nuclides. These include 31 nuclides with very long half lives (over 80 million years) and 257 which are formally considered as "stable"[2]. About 30 of these "stable" isotopes have actually been observed to decay, but with half lives too long to be estimated so far. This leaves 227 nuclides that have not been observed to decay at all. Numbers of isotopes per element

Of the 80 elements with a stable isotope, the largest number of stable isotopes observed for any element is ten (for the element tin). Xenon is the only...
tracking img